Citation: Liu Na, Shi Liangfeng, Han Xianghao, Qi Qiao-Yan, Wu Zong-Quan, Zhao Xin. A heteropore covalent organic framework for adsorptive removal of Cd(Ⅱ) from aqueous solutions with high efficiency[J]. Chinese Chemical Letters, ;2020, 31(2): 386-390. doi: 10.1016/j.cclet.2019.06.050 shu

A heteropore covalent organic framework for adsorptive removal of Cd(Ⅱ) from aqueous solutions with high efficiency

Liu Na ^a ,
Shi Liangfeng ^a,b,1 ,
Han Xianghao ^b,1 ,
Qi Qiao-Yan ^b ,
Wu Zong-Quan ^a,*, ,
Zhao Xin ^b,*,

a.
Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, and Anhui Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, Hefei University of Technology, Hefei 230009, China
b.
CAS Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

zqwu@hfut.edu.cn

xzhao@sioc.ac.cn

Received Date: 7 May 2019
Revised Date: 18 June 2019
Accepted Date: 27 June 2019
Available Online: 27 June 2019

Figures(5)

A heteropore covalent organic framework (COF) integrating tetraphenylethene skeleton and catechol segment is designed and synthesized. It exhibits extremely high stability in water under different pH conditions, which makes it an excellent material for adsorptive removal of Cd(Ⅱ) from aqueous solutions with very fast adsorption kinetics, high uptake capacity, and good recyclability.
- Covalent organic frameworks,
- Heteropore,
- Hierarchical porosity,
- Cd(Ⅱ) removal,
- Water treatment
1. [1]
  (a) R.P. Schwarzenbach, B.I. Escher, K. Fenner, et al., Science 313 (2006) 1072-1077;
  (b) M.P. Waalkes, J. Inorg, Biochem. 79 (2000) 241-244;
  (c) M. Hua, S. Zhang, B. Pan, et al., J. Hazard. Mater. 211-212 (2012) 317-331;
  (d) P. Miretzky, A.F. Cirelli, J. Hazard. Mater. 167 (2009) 10-23;
  (e) M.T. Hayat, M. Nauman, N. Nazir, S.Ali N. Bangash, Environmental hazards of cadmium: past, present, and future, in: M. Hasanuzzaman, M.N.V. Prasad, M. Fujita (Eds.), Cadmium Toxicity and Tolerance in Plants, Academic Press, New York, 2019, pp. 163-183;
  (f) H. Liu, G. Liu, Z. Yuan, et al., Mar. Pollut. Bull. 140 (2019) 388-394;
  (g) P.K. Samantaray, S. Baloda, G. Madras, S. Bose, J. Mater. Chem. A 6 (2018) 16664-16679.
2. [2]
  (a) H. Yamada, T. Miyahara, Y. Sasaki, Mutat. Res. Lett. 302 (1993) 137-145;
  (b) I.A. Darwish, D.A. Blake, Anal. Chem. 73 (2001) 1889-1895;
  (c) K. Nogawa, E. Kobayashi, Y. Okubo, Y. Suwazono, Biometals 17 (2004) 581-587;
  (d) S. Khan, Q. Cao, Y.M. Zheng, Y.Z. Huang, Y.G. Zhu, Environ. Pollut. 152 (2008) 686-692;
  (e) R. Zha, R. Nadimicherla, X. Guo, J. Mater. Chem A 2 (2014) 13932-13941.
3. [3]
  (a) S. Rodrigues, N. Munichandraiah, A.K. Shukla, J. Power Sources 87 (2000) 12-20;
  (b) S. Ghatak, G. Chakraborty, M. Sinha, S.K. Pradhan, A.K. Meikap, Physica B 406 (2011) 3261-3266.
4. [4]
  (a) C. Zhu, Y. Guo, Y. Yang, et al., J. Environ. Eng. Technol. 8 (2018) 58-64;
  (b) Y. Lan, R. Liang, X. Zhao, et al., Acta Sci. Circumstantiae 37 (2017) 3602-3612.
5. [5]
  (a) A. Özverdi, M. Erdem, J. Hazard. Mater. B 137 (2006) 626-632;
  (b) J. Koelmel, M.N.V. Prasad, G. Velvizhi, S.K. Butti, S.V. Mohan, Metalliferous waste in India and knowledge explosion in metal recovery techniques and processes for the prevention of pollution, in: M.N.V. Prasad, K. Shih (Eds.), Environmental Materials and Waste, Academic Press, New York, 2016, pp. 339-390;
  (c) D. Purkayastha, U. Mishra, S. Biswas, J. Water Process. Eng. 2 (2014) 105-128;
  (d) F. Fu, Q. Wang, J. Environ. Manag. 92 (2011) 407-418.
6. [6]
  (a) J. Shao, J.D. Gu, L. Peng, et al., J. Hazard. Mater. 272 (2014) 83-88;
  (b) M.Q. Jiang, X.Y. Jin, X.Q. Lu, Z.L. Chen, Desalination 252 (2010) 33-39;
  (c) P. Pavasant, R. Apiratikul, V. Sungkhum, et al., Bioresour. Technol. 97 (2006) 2321-2329;
  (d) Z. Feng, S. Zhu, D.R. Martins de Godoi, A.C.S. Samia, D. Scherson, Anal. Chem. 84 (2012) 3764-3770.
7. [7]
  (a) E. Samper, M. Rodríguez, M.A. De la Rubia, D. Prats, Sep. Purif. Technol. 65 (2009) 337-342;
  (b)J.H. Huang, G.M. Zeng, C.F. Zhou, et al., J.Hazard.Mater.183 (2010) 287-293;
  (c) D.J. Ennigrou, L. Gzara, M.R. Ben Romdhane, M. Dhahbi, Desalination 246 (2009) 363-369.
8. [8]
  (a) L.E. Kanagy, B.M. Johnson, J.W. Castle, J.H. Rodgers Jr., Bioresour. Technol. 99 (2008) 1877-1885;
  (b) H.A. Qdais, H. Moussa, Desalination 164 (2004) 105-110.
9. [9]
  (a) A. Üçer, A. Uyanik, Ş.F. Aygün, Sep. Purif. Technol. 47 (2006) 113-118;
  (b) B.E.Reed, S.Arunachalam, B.Thomas, Environ.Prog.Sustain. 13 (1994)60-64;
  (c) B. Xiao, K.M. Thomas, Langmuir 21 (2005) 3892-3902.
10. [10]
  (a) J.L. Weidman, R.A. Mulvenna, B.W. Boudouris, W.A. Phillip, ACS Appl. Mater. Interfaces 9 (2017) 19152-19160;
  (b) M.X. Tan, Y.N. Sum, J.Y. Ying, Y. Zhang, EnergyEnviron. Sci. 6 (2013) 3254-3259;
  (c) H. Zhu, X. Tan, L. Tan, et al., ACS Sustain. Chem. Eng. 6 (2018) 5206-5213.
11. [11]
  (a) Y. Wang, G. Ye, H. Chen, et al., J. Mater. Chem. A 3 (2015) 15292-15298;
  (b) J. Zhang, Z. Xiong, C. Li, C. Wu, J. Mol. Liq. 221 (2016) 43-50;
  (c) C. Liu, P. Wang, X. Liu, et al., Chem. -Asian J. 14 (2019) 261-268;
  (d) J. Li, X. Wang, G. Zhao, et al., Chem. Soc. Rev. 47 (2018) 2322-2356.
12. [12]
  (a) A.P. Côté, A.I. Benin, N.W. Ockwig, M. O'Keeffe, A.J. Matzger, O.M. Yaghi, Science 310 (2005) 1166-1170;
  (b) S.Y. Ding, W. Wang, Chem. Soc. Rev. 42 (2013) 548-568;
  (c) P.J. Waller, F. Gándara, O.M. Yaghi, Acc. Chem. Res. 48 (2015) 3053-3063;
  (d) S.Kandambeth, K. Dey, R. Banerjee, J.Am. Chem. Soc.141 (2019) 1807-1822.
13. [13]
  (a) M.S. Lohse, T. Bein, Adv. Funct. Mater. 28 (2018) 1705553;
  (b) Y. Song, Q. Sun, B. Aguila, S. Ma, Adv. Sci. 6 (2019) 1801410;
  (c) N. Huang, P. Wang, D. Jiang, Nat. Rev. Mater. 1 (2016) 16068;
  (d) M.X. Wu, Y.W. Yang, Chin. Chem. Lett. 28 (2017) 1135-1143.
14. [14]
  (a) S.Y. Ding, M. Dong, Y.W. Wang, et al., J. Am. Chem. Soc. 138 (2016) 3031-3037;
  (b) N. Huang, L. Zhai, H. Xu, D. Jiang, J. Am. Chem. Soc. 139 (2017) 2428-2434;
  (c) Q. Sun, B. Aguila, J. Perman, et al., J. Am. Chem. Soc.139 (2017) 2786-2793;
  (d) K. Leus, K. Folens, N.R. Nicomel, et al., J. Hazard. Mater. 353 (2018) 312-319;
  (e) Q. Lu, Y. Ma, H. Li, et al., Angew. Chem. Int. Ed. 57 (2018) 6042-6048;
  (f) Z.A. Ghazi, A.M. Khattak, R. Iqbal, et al., New J. Chem. 42 (2018) 10234-10242;
  (g) F.Z. Cui, R.R. Liang, Q.Y. Qi, G.F. Jiang, X. Zhao, Adv. Sustain. Syst. (2019) 1800150.
15. [15]
  (a) X.Y. Yang, L.H. Chen, Y. Li, et al., Chem. Soc. Rev. 46 (2017) 481-558;
  (b) S. Lopez-Orozco, A. Inayat, A. Schwab, T. Selvam, W. Schwieger, Adv. Mater. 23 (2011) 2602-2615;
  (c) Y. Li, Z.Y. Fu, B.L. Su, Adv. Funct. Mater. 22 (2012) 4634-4667.
16. [16]
  R.R. Liang, X. Zhao, Org. Chem. Front. 5 (2018) 3341-3356. doi: 10.1039/C8QO00830B
17. [17]
  (a) D.B. Shinde, S. Kandambeth, P. Pachfule, R.R. Kumar, R. Banerjee, Chem. Commun. 51 (2015) 310-313;
  (b) A. Halder, S. Kandambeth, B.P. Biswal, et al., Angew. Chem. Int. Ed. 55 (2016) 7806-7810.
18. [18]
  Dassault Systèmes BIOVIA, Materials Studio 8.0, Dassault Systèmes San Diego, (2014).
19. [19]
  (a) T.Y. Zhou, S.Q. Xu, Q. Wen, Z.F. Pang, X. Zhao, J. Am. Chem. Soc. 136 (2014) 15885-15888;
  (b) Z.F. Pang, T.Y. Zhou, R.R. Liang, Q.Y. Qi, X. Zhao, Chem. Sci. 8 (2017) 3866-3870.
20. [20]
  X. Chen, M. Addicoat, E. Jin, et al., J. Am. Chem. Soc. 137 (2015) 3241-3247. doi: 10.1021/ja509602c
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