Citation: Xue Yuan, Liu Jinbao, Xie Maiying, Chen Fengfei, Zhou Mingan, Lin Hualin, Zhang Fan, Liu Shizhou, Wu Zhiqiao, Han Sheng. Effects of the chemical structure of surfactants on the stability of naphthenic oil-based metalworking fluids[J]. Chinese Chemical Letters, ;2020, 31(2): 345-348. doi: 10.1016/j.cclet.2019.06.031 shu

Effects of the chemical structure of surfactants on the stability of naphthenic oil-based metalworking fluids

Xue Yuan ^a ,
Liu Jinbao ^b ,
Xie Maiying ^a ,
Chen Fengfei ^a ,
Zhou Mingan ^a ,
Lin Hualin ^a ,
Zhang Fan ^a ,
Liu Shizhou ^c ,
Wu Zhiqiao ^a,*, ,
Han Sheng ^a,*,

a.
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China
b.
Department of Science and Technology, Shanghai Urban Construction Vocational College, Shanghai 201415, China
c.
College of Chemistry and Chemical Engineering, Shanxi Datong University, Datong 037009, China

qiaoqiaoyizu@163.com

hansheng654321@sina.com

Received Date: 20 May 2019
Revised Date: 9 June 2019
Accepted Date: 18 June 2019
Available Online: 19 June 2019

Figures(3)

In this study, various nonionic surfactants (NS) with different ethylene oxide (EO) numbers and tail lengths and its binary blends with anionic surfactants (AS) were used as emulsifiers for naphthenic oil to form the microemulsion metalworking fluids (MWFs), and the effects of them on the stability of the emulsion system were investigated by formulation triangle method. The results indicated that binary complex surfactants of NS and AS as emulsifiers exhibited better emulsifying effect than that of single NS. NS with different EO numbers and tail lengths presented various emulsifying effects. NS (EO = 10) exhibited the greatest number of stable formulations, especially the TX-10, but no linear relationship existed between the number of stable formulations and the tail length of NS. In addition, aromatic primary alcohol ethoxylate (APAE) series surfactants containing benzene groups similar to the cycloalkanes in the naphthenic oil so that presented the best emulsifying affect and the greatest number of stable formulations. The co-surfactant of sodium dodecyl benzene sulfonate (SDBS) binary blends with NS exerted the best synergistic effect, and the stable formulations numbers were ranged from 5 to 7, next sodium stearate (SS) comes last followed by sodium dodecyl sulfate (SDS-1) and sodium dodecyl sulfonate (SDS-2).
- Metal working fluid,
- Emulsion stability,
- Emulsifying effects,
- Stable formulations,
- Naphthenic oil
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