Citation: Yan Jingjing, Zhu Dazhang, Lv Yaokang, Xiong Wei, Liu Mingxian, Gan Lihua. Water-in-salt electrolyte ion-matched N/O codoped porous carbons for high-performance supercapacitors[J]. Chinese Chemical Letters, ;2020, 31(2): 579-582. doi: 10.1016/j.cclet.2019.05.035 shu

Water-in-salt electrolyte ion-matched N/O codoped porous carbons for high-performance supercapacitors

Yan Jingjing ^a ,
Zhu Dazhang ^a ,
Lv Yaokang ^b ,
Xiong Wei ^c ,
Liu Mingxian ^a,d,*, ,
Gan Lihua ^a,*,

a.
Shanghai Key Lab of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China
b.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
c.
Key Laboratory for Green Chemical Process of Ministry of Education, School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430073, China
d.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

liumx@tongji.edu.cn

ganlh@tongji.edu.cn

Received Date: 11 April 2019
Revised Date: 7 May 2019
Accepted Date: 20 May 2019
Available Online: 20 May 2019

Figures(4)

Pore size and distribution in carbon-based materials are regarded to be a key factor to affect the electrochemical capacitive performances of the resultant electrodes. In this study, nitrogen and oxygen codoped porous carbons (NOPCs) are fabricated based on a simple Schiff-base reaction between m-phenylenediamine and terephthalaldehyde. The NOPCs have tunable morphologies, high surface areas, abundant heteroatom doping. More importantly, the carbons show a dominant micropores of 0.5-0.8 nm, comparable to the ionic sizes of LiTFSI (Li⁺ 0.069 nm; TFSI-0.79 nm) water-in-salt electrolyte with a high potential window of 2.2 V. Consequently, the fabricated symmetric supercapacitor gives a high energy output of 30.5 Wh/kg at 1 kW/kg, and high stability after successive 10, 000 cycles with ~96.8% retention. This study provides promising potential to develop high-energy supercapacitors.
- N/O Codoped Porous carbon,
- Water-in-salt electrolyte,
- Pore/ion size matching,
- Symmetrical supercapacitor,
- High energy density
1. [1]
  D. Jia, X. Yu, H. Tan, et al., J. Mater. Chem. A 5 (2017) 1516-1525. doi: 10.1039/C6TA09229B
2. [2]
  L. Miao, X. Qian, D. Zhu, et al., Chin. Chem. Lett. 30 (2019) 1445-1449. doi: 10.1016/j.cclet.2019.03.010
3. [3]
  H. Yu, H. Xia, J. Zhang, et al., Chin. Chem. Lett. 29 (2018) 834-836. doi: 10.1016/j.cclet.2018.04.008
4. [4]
  J. Zhao, Y. Li, F. Huang, et al., J. Electroanal. Chem. 823 (2018) 474-481. doi: 10.1016/j.jelechem.2018.06.042
5. [5]
  X. He, X. Li, H. Ma, et al., J. Power Sources 340 (2017) 183-191. doi: 10.1016/j.jpowsour.2016.11.073
6. [6]
  X. He, H. Zhang, H. Zhang, et al., J. Mater. Chem. A 2 (2014) 19633-19640. doi: 10.1039/C4TA03323J
7. [7]
  Z. Liu, Z. Zhou, W. Xiong, et al., Langmuir 34 (2018) 10389-10396. doi: 10.1021/acs.langmuir.8b02156
8. [8]
  J. Zhao, Y. Li, X. Chen, et al., Electrochim. Acta 292 (2018) 458-467. doi: 10.1016/j.electacta.2018.09.178
9. [9]
  Y. Liu, N. Liu, L. Yu, et al., Chem. Eng. J. 362 (2019) 600-608. doi: 10.1016/j.cej.2019.01.058
10. [10]
  Y. Zhu, N. Li, T. Lv, et al., J. Mater. Chem. A 6 (2018) 941-947. doi: 10.1039/C7TA09154K
11. [11]
  H. Peng, G. Qian, N. Li, et al., Adv. Sci. 5 (2018) 1800784. doi: 10.1002/advs.201800784
12. [12]
  J. Liu, N.P. Wickramaratne, S.Z. Qiao, et al., Nat. Mater. 14 (2015) 763. doi: 10.1038/nmat4317
13. [13]
  J. Pang, W. Zhang, H. Zhang, et al., Carbon 132 (2018) 280-293. doi: 10.1016/j.carbon.2018.02.077
14. [14]
  S. Huo, M. Liu, L. Wu, et al., J. Power Sources 387 (2018) 81-90. doi: 10.1016/j.jpowsour.2018.03.061
15. [15]
  D. Xue, D. Zhu, W. Xiong, et al., ACS Sustainable Chem. Eng. 7 (2019) 7024-7034. doi: 10.1021/acssuschemeng.8b06774
16. [16]
  G. Zhu, L. Ma, H. Lv, et al., Nanoscale 9 (2017) 1237-1243. doi: 10.1039/C6NR08139H
17. [17]
  D. Reber, R.-S. Kühnel, C. Battaglia, Sustain. Energ. Fuels 1 (2017) 2155-2161. doi: 10.1039/C7SE00423K
18. [18]
  A. Gambou-Bosca, D. Bélanger, J. Power Sources 326 (2016) 595-603. doi: 10.1016/j.jpowsour.2016.04.088
19. [19]
  G. Sun, W. Song, X. Liu, et al., Electrochim. Acta 56 (2011) 9248-9256. doi: 10.1016/j.electacta.2011.07.139
20. [20]
  L. Zhang, Y. Guo, K. Shen, et al., J. Mater. Chem. A 7 (2019) 9163-9172. doi: 10.1039/C9TA00781D
21. [21]
  S. Dong, X. He, H. Zhang, et al., J. Mater. Chem. A 6 (2018) 15954-15960. doi: 10.1039/C8TA04080J
22. [22]
  X. Xie, X. He, H. Zhang, et al., Chem. Eng. J. 350 (2018) 49-56. doi: 10.1016/j.cej.2018.05.011
23. [23]
  C. Wang, D. Wu, H. Wang, et al., J. Mater. Chem. A 6 (2018) 1244-1254. doi: 10.1039/C7TA07579K
24. [24]
  H. Luo, P. Xiong, J. Xie, et al., Adv. Funct. Mater. 28 (2018) 1803075. doi: 10.1002/adfm.201803075
25. [25]
  Q. Wang, B. Qin, X. Zhang, et al., J. Mater. Chem. A 6 (2018) 19653-19663. doi: 10.1039/C8TA07563H
26. [26]
  C. Ramasamy, J. Palma del Val, M. Anderson, J. Power Sources 248 (2014) 370-377. doi: 10.1016/j.jpowsour.2013.09.078
27. [27]
  K. Fic, G. Lota, M. Meller, et al., Energy Environ. Sci. 5 (2012) 5842-5850. doi: 10.1039/C1EE02262H
28. [28]
  Q. Dou, S. Lei, D.-W. Wang, et al., Energy Environ. Sci. 11 (2018) 3212-3219. doi: 10.1039/C8EE01040D
29. [29]
  L. Smith, B. Dunn, Science 350 (2015) 918. doi: 10.1126/science.aad5575
30. [30]
  L. Suo, O. Borodin, T. Gao, et al., Science 350 (2015) 938-943. doi: 10.1126/science.aab1595
31. [31]
  L. Suo, O. Borodin, W. Sun, et al., Angew. Chem. Int. Ed. 55 (2016) 7136-7141. doi: 10.1002/anie.201602397
32. [32]
  P. Simon, Y. Gogotsi, Nat. Mater. 7 (2008) 845-854. doi: 10.1038/nmat2297
33. [33]
  L. Qiu, Y. Jiang, X. Sun, et al., J. Mater. Chem. A 2 (2014) 15132-15138. doi: 10.1039/C4TA02979H
34. [34]
  R. Zhang, X. Jing, Y. Chu, et al., J. Mater. Chem. A 6 (2018) 17730-17739. doi: 10.1039/C8TA06471G
35. [35]
  L. Yao, Q. Wu, P. Zhang, et al., Adv. Mater. 30 (2018) 1706054. doi: 10.1002/adma.201706054
36. [36]
  T. Guan, K. Li, J. Zhao, et al., J. Mater. Chem. A 5 (2017) 15869-15878. doi: 10.1039/C7TA02966G
37. [37]
  L. Miao, D. Zhu, M. Liu, et al., Electrochim. Acta 274 (2018) 378-388. doi: 10.1016/j.electacta.2018.04.100
38. [38]
  M. Liu, J. Niu, Z. Zhang, et al., Nano Energy 51 (2018) 366-372. doi: 10.1016/j.nanoen.2018.06.037
39. [39]
  M. Liu, F. Zhao, D. Zhu, et al., Mater. Chem. Phys. 211 (2018) 234-241. doi: 10.1016/j.matchemphys.2018.02.030
40. [40]
  N. Zhang, F. Liu, S.-D. Xu, et al., J. Mater. Chem. A 5 (2017) 22631-22640. doi: 10.1039/C7TA07488C
41. [41]
  S. Witomska, Z. Liu, W. Czepa, et al., J. Am. Chem. Soc. 141 (2018) 482-487.
42. [42]
  J. Zhao, Y. Li, G. Wang, et al., J. Mater. Chem. A 5 (2017) 23085-23093. doi: 10.1039/C7TA07010A
43. [43]
  J. Zhao, J. Gong, Y. Li, et al., Acta Chim. Sinica 76 (2018) 107-112. doi: 10.6023/A17090422
44. [44]
  Z. Song, H. Duan, L. Li, et al., Chem. Eng. J. 372 (2019) 1216-1225. doi: 10.1016/j.cej.2019.05.019
45. [45]
  D. Zhu, J. Jiang, D. Sun, et al., J. Mater. Chem. A 6 (2018) 12334-12343. doi: 10.1039/C8TA02341G
46. [46]
  D. Qu, J. Power Sources 109 (2002) 403-411. doi: 10.1016/S0378-7753(02)00108-8
47. [47]
  K.M. Horax, S. Bao, M. Wang, et al., Chin. Chem. Lett. 28 (2017) 2290-2294. doi: 10.1016/j.cclet.2017.11.004
48. [48]
  F. Wei, X. He, H. Zhang, et al., J. Power Sources 428 (2019) 8-12. doi: 10.1016/j.jpowsour.2019.04.096
49. [49]
  J. Jiang, P. Nie, S. Fang, et al., Chin. Chem. Lett. 29 (2018) 624-628. doi: 10.1016/j.cclet.2018.01.029
50. [50]
  X. He, X. Xie, J. Wang, et al., Nanoscale 11 (2019) 6610-6619. doi: 10.1039/C9NR00068B
51. [51]
  H. Li, T. Lv, H. Sun, et al., Nat. Commun. 10 (2019) 536. doi: 10.1038/s41467-019-08320-z
1. [1]
  Xingjie Li , Chengjun Yi , Weifei Hu , Huishan Zhang , Jiale Xia , Yuanyuan Li , Jinping Liu . Emerging sulfide-polymer composite solid electrolyte membranes. Chinese Chemical Letters, 2025, 36(6): 110215-. doi: 10.1016/j.cclet.2024.110215
2. [2]
  Jieqiong Qin , Zhi Yang , Jiaxin Ma , Liangzhu Zhang , Feifei Xing , Hongtao Zhang , Shuxia Tian , Shuanghao Zheng , Zhong-Shuai Wu . Interfacial assembly of 2D polydopamine/graphene heterostructures with well-defined mesopore and tunable thickness for high-energy planar micro-supercapacitors. Chinese Chemical Letters, 2024, 35(7): 108845-. doi: 10.1016/j.cclet.2023.108845
3. [3]
  Yuchen Wang , Yaoyu Liu , Xiongfei Huang , Guanjie He , Kai Yan . Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(8): 109301-. doi: 10.1016/j.cclet.2023.109301
4. [4]
  Wenhao Feng , Chunli Liu , Zheng Liu , Huan Pang . In-situ growth of N-doped graphene-like carbon/MOF nanocomposites for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(12): 109552-. doi: 10.1016/j.cclet.2024.109552
5. [5]
  Peng Wang , Guanyu Zhao , Yicai Pan , Yujing Li , Chenxi Fu , Shipeng Sun , Junqi Gai , Jinping Mu , Xue Bai , Xiaohui Li , Jinfeng Sun , Xiaodong Shi , Rui He . Dual-salt electrolyte strategy enables stable interface reaction and high-performance lithium-ion batteries at low temperature. Chinese Chemical Letters, 2025, 36(11): 111190-. doi: 10.1016/j.cclet.2025.111190
6. [6]
  Xin Li , Ling Zhang , Yunyan Fan , Shaojing Lin , Yong Lin , Yongsheng Ying , Meijiao Hu , Haiying Gao , Xianri Xu , Zhongbiao Xia , Xinchuan Lin , Junjie Lu , Xiang Han . Carbon interconnected microsized Si film toward high energy room temperature solid-state lithium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109776-. doi: 10.1016/j.cclet.2024.109776
7. [7]
  Qingyun Hu , Wei Wang , Junyuan Lu , He Zhu , Qi Liu , Yang Ren , Hong Wang , Jian Hui . High-throughput screening of high energy density LiMn_1-xFe_xPO₄ via active learning. Chinese Chemical Letters, 2025, 36(2): 110344-. doi: 10.1016/j.cclet.2024.110344
8. [8]
  Lin Zhang , Jianlong Li , Maoyuan Hu , Yao Xu , Xiaoli Xiong , Zhaoyu Jin . MOF-derived beaded stream-like nitrogen and phosphorus-codoped carbon-coated Fe₃O₄ nanocomposites via lattice-oxygen-mediated mechanism for efficient water oxidation. Chinese Chemical Letters, 2025, 36(8): 111123-. doi: 10.1016/j.cclet.2025.111123
9. [9]
  Bin Zhao , Heping Luo , Jiaqing Liu , Sha Chen , Han Xu , Yu Liao , Xue Feng Lu , Yan Qing , Yiqiang Wu . S-doped carbonized wood fiber decorated with sulfide heterojunction-embedded S, N-doped carbon microleaf arrays for efficient high-current-density oxygen evolution. Chinese Chemical Letters, 2025, 36(5): 109919-. doi: 10.1016/j.cclet.2024.109919
10. [10]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
11. [11]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
12. [12]
  Xinyu Huai , Jingxuan Liu , Xiang Wu . Cobalt-Doped NiMoO4 Nanosheet for High-performance Flexible Supercapacitor. Chinese Journal of Structural Chemistry, 2023, 42(10): 100158-100158. doi: 10.1016/j.cjsc.2023.100158
13. [13]
  Hongren RONG , Gexiang GAO , Zhiwei LIU , Ke ZHOU , Lixin SU , Hao HUANG , Wenlong LIU , Qi LIU . High-performance supercapacitor based on 1D cobalt-based coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1183-1195. doi: 10.11862/CJIC.20250034
14. [14]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
15. [15]
  Yanhua Peng , Xin Yu , Ting Wang . Adaptive nanoconfined Fenton-like reactions: Tailoring carbon pathways for sustainable water treatment and energy harvesting. Chinese Chemical Letters, 2024, 35(12): 110198-. doi: 10.1016/j.cclet.2024.110198
16. [16]
  Chong Tang , Zhong Qiu , Chen Li , Tengfei Zhang , Renhong Chen , Yifa Sheng , Xinhui Xia , Yongqi Zhang , Jun Liu . Rational synthesis of vertical graphene supported TiN@N-Li₄Ti₅O₁₂ as advanced high-rate electrodes for lithium-ion batteries. Chinese Chemical Letters, 2025, 36(11): 110589-. doi: 10.1016/j.cclet.2024.110589
17. [17]
  Canglong Li , Tao Liao , Dongping Chen , Tiancheng You , Xiaozhi Jiang , Minghan Xu , Huaming Yu , Gang Zhou , Guanghui Li , Yuejiao Chen . Fabrication of carbon-coated V₂O_5-x nanoparticles by plasma-enhanced chemical vapor deposition for high-performance aqueous zinc-ion battery composite cathodes. Chinese Chemical Letters, 2025, 36(12): 110557-. doi: 10.1016/j.cclet.2024.110557
18. [18]
  Liangju Zhao , Shiyu Qin , Fei Wu , Limin Zhu , Qing Han , Lingling Xie , Xuejing Qiu , Hongliang Wei , Lanhua Yi , Xiaoyu Cao . Polycarbonyl conjugated porous polyimide as anode materials for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(8): 110246-. doi: 10.1016/j.cclet.2024.110246
19. [19]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
20. [20]
  Mei-Chen Liu , Qing-Song Liu , Yi-Zhou Quan , Jia-Ling Yu , Gang Wu , Xiu-Li Wang , Yu-Zhong Wang . Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries. Chinese Chemical Letters, 2024, 35(8): 109123-. doi: 10.1016/j.cclet.2023.109123

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1888)
HTML views(158)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142