Citation: Zhou Jing, Ding Li, Zhao Fengqi, Wang Bozhou, Zhang Junlin. Thermal studies of novel molecular perovskite energetic material (C₆H₁₄N₂)[NH₄(ClO₄)₃][J]. Chinese Chemical Letters, ;2020, 31(2): 554-558. doi: 10.1016/j.cclet.2019.05.008 shu

Thermal studies of novel molecular perovskite energetic material (C₆H₁₄N₂)[NH₄(ClO₄)₃]

Zhou Jing ^a ,
Ding Li ^a,*, ,
Zhao Fengqi ^a ,
Wang Bozhou ^a ,
Zhang Junlin ^a,b,*,

a.
Xi'an Modern Chemistry Research Institute, Xi'an 710065 China
b.
Department of Chemistry, Technische Universität München, Garching bei München 85748, Germany

dingli403@sina.com

junlin-111@163.com

Received Date: 27 February 2019
Revised Date: 4 May 2019
Accepted Date: 6 May 2019
Available Online: 6 May 2019

Figures(6)

(C₆H₁₄N₂)[NH₄(ClO₄)₃] is a newly developed porous hybrid inorganic-organic framework material with easy access and excellent detonation performances, however, its thermal properties is still unclear and severely hampered further applications. In this study, thermal behaviors and non-isothermal decomposition reaction kinetics of (C₆H₁₄N₂)[NH₄(ClO₄)₃] were investigated systematically by the combination of differential scanning calorimetry (DSC) and simultaneous thermal analysis methods. In-situ FTIR spectroscopy technology was applied for investigation of the structure changes of (C₆H₁₄N₂)[NH₄(ClO₄)₃] and some selected referents for better understanding of interactions between different components during the heating process. Experiment results indicated that the novel molecular perovskite structure renders (C₆H₁₄N₂)[NH₄(ClO₄)₃] better thermal stability than most of currently used energetic materials. Under high temperatures, the stability of the cage skeleton constructed by NH₄⁺ and ClO₄^- ionsdetermined the decomposition process rather than organic moiety confined in the skeleton. The simple synthetic method, good detonation performances and excellent thermal properties make (C₆H₁₄N₂)[NH₄(ClO₄)₃] an ideal candidate for the preparation of advanced explosives and propellants.
- Cage skeleton,
- DSC-TG,
- In-situ FTIR,
- Inorganic-organic framework material,
- Thermal behaviors
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Thermal studies of novel molecular perovskite energetic material (C₆H₁₄N₂)[NH₄(ClO₄)₃]