Citation: Hu Qiang, Zhao Chen, Zhang Zhejuan, Guo Jun, Yu Chenlu, Sun Zhuo, Piao Xianqing. Sonochemical synthesis of silver nanoparticles coated copper wire for low-temperature solid state bonding on silicon substrate[J]. Chinese Chemical Letters, ;2019, 30(7): 1455-1459. doi: 10.1016/j.cclet.2019.04.050 shu

Sonochemical synthesis of silver nanoparticles coated copper wire for low-temperature solid state bonding on silicon substrate

School of Physics & Material Science, Engineering Research Center for Nanophotonics & Advanced Instrument, Ministry of Education, East China Normal University, Shanghai 200062, China

zjzhang@phy.ecnu.edu.cn

Received Date: 29 November 2018
Revised Date: 31 March 2019
Accepted Date: 15 April 2019
Available Online: 18 July 2019

Figures(6)

Silver nanoparticles (AgNPs) are directly grown on surface of ~25 μm copper wire by ultrasound-assisted chemical reduction. Silver nitrate is used as precursors, when polyvinylpyrrolidone (PVP) is added as a controller of the dimension of AgNPs. Influence of growth parameters such as precursor's concentration, ratio proportion of PVP and ultra-sonication on the growth of AgNPs coating are determined. The best morphology, size of the AgNPs are observed on copper wire. The results show that the copper wire coated with AgNPs of ~100 nm diameter exhibits good antioxidation and ohmic contact after sinter on Si substrate at a temperature as low as 320 ℃, is especially suitable as a substitute for silver paste electrode used in silicon solar cells.
- Sonochemistry,
- Ag-Cu copper wire,
- Low-temperature sintering,
- Solar cells,
- Polyvinylpyrrolidone
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沈阳化工大学材料科学与工程学院沈阳 110142