Citation: Zhao Yujun, Li Sijia, Wang Zheng, Wang Shengnian, Wang Shengping, Ma Xinbin. New ZnCe catalyst encapsulated in SBA-15 in the production of 1, 3-butadiene from ethanol[J]. Chinese Chemical Letters, ;2020, 31(2): 535-538. doi: 10.1016/j.cclet.2019.04.038 shu

New ZnCe catalyst encapsulated in SBA-15 in the production of 1, 3-butadiene from ethanol

Zhao Yujun ^a,*, ,
Li Sijia ^a ,
Wang Zheng ^a ,
Wang Shengnian ^b,*, ,
Wang Shengping ^a ,
Ma Xinbin ^a

a.
Key Laboratory for Green Chemical Technology of Ministry of Education. Collaborative Innovation Center of Chemical Science and Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
b.
Chemical Engineering, Institute for Micromanufacturing, Louisiana Tech University, Ruston, LA 71272, United States

yujunzhao@tju.edu.cn

swang@latech.edu

Received Date: 14 March 2019
Revised Date: 11 April 2019
Accepted Date: 16 April 2019
Available Online: 17 April 2019

Figures(5)

ZnO-CeO₂/SBA-15 catalysts were prepared by two kinds of solid-state grinding method and used for the production of 1, 3-butadiene (1, 3-BD) from ethanol. A mixture of SBA-15 (with or without organic template) and metal precursors were ground in solid-state. The obtained catalysts were characterized by TG, N₂ adsorption-desorption, TEM, XRD, Py-FTIR and NH₃-TPD techniques. Superior dispersion of metal oxides and more exposed acid sites were achieved on the catalyst 10Zn₁Ce₅-AS with the presence of organic template in SBA-15 during the solid-state grinding process. The catalytic performance was evaluated in a fixed-bed reactor and a 1, 3-butadiene selectivity of as high as 45% is achieved. This is attributed to the coupling effect of Zn and Ce species in the mesopores of SBA-15, in which Zn promotes ethanol dehydrogenation and Ce enhances aldol-condensation, respectively. Additionally, solvent-free method inspires new catalyst synthesis strategy for the production of 1, 3-butadiene from ethanol.
- 1, 3-Butadiene,
- Ethanol,
- SBA-15,
- Dehydrogenation,
- Aldol-condensation
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