Citation: Liu Xiaoyun, Wang Liying, Chen Siyuan, Zha Liusheng. Silver nanoparticles embedded temperature-sensitive nanofibrous membrane as a smart free-standing SERS substrate[J]. Chinese Chemical Letters, ;2019, 30(12): 2021-2026. doi: 10.1016/j.cclet.2019.04.031 shu

Silver nanoparticles embedded temperature-sensitive nanofibrous membrane as a smart free-standing SERS substrate

a.
Research Center for Analysis and Measurement, Donghua University, Shanghai 201620, China
b.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering, Donghua University, Shanghai 201620, China

lszha@dhu.edu.cn

Received Date: 21 March 2019
Accepted Date: 12 April 2019
Available Online: 20 December 2019

Figures(4)

To develop a smart free-standing surface enhanced Raman scattering (SERS) substrate, silver nanoparticles (AgNPs) embedded temperature-sensitive nanofibrous membrane was fabricated by electrospinning their aqueous solution containing the copolymer poly(N-isopropylacrylamide-co-N-hydroxymethylacrylamide), followed by heat treatment to form crosslinking structure within its constituent nanofibers. To avoid negative effect of the additive like stabilizer and the reactant like reductant on their SERS efficiency, the AgNPs were in-situ synthesized through reducing Ag⁺ ions dissolved in the polymer solution by ultraviolet irradiation. The prepared hybrid nanofibrous membrane with high stability in aqueous medium can reach its swelling or deswelling equilibrium state within 15 seconds with the medium temperature changing between 25℃ and 50℃ alternately. When it was used as a free-standing SERS substrate, 10^-12 mol/L of 4-nitrothiophenol in aqueous solution can be detected at room temperature, and elevating detection temperature can further lower its low detection limit. Since its generated SERS signal has desirable reproducibility, it can be used as SERS substrate for quantitative analysis. Moreover, the hybrid membrane as SERS substrate is capable of real-time monitoring the reduction of 4-nitrothiophenol into 4-aminothiophenol catalyzed by its embedded AgNPs, and the detected intermediate indicates that the reaction proceeds via a condensation route.
- Nanofibrous membrane,
- Silver nanoparticles,
- Electrospinning,
- Temperature-sensitiveness,
- SERS substrate
1. [1]
  Q.H. Tran, V.Q. Nguyen, A.T. Le, Adv. Nat. Sci:Nanosci. Nanotechnol. 4 (2013) 033001. doi: 10.1088/2043-6262/4/3/033001
2. [2]
  S. Abalde-Cela, S. Carregal-Romero, J.P. Coelho, A. Guerrero-Martinez, Adv. Colloid Interfac. 233 (2016) 255-270. doi: 10.1016/j.cis.2015.05.002
3. [3]
  H.N. Bich, N. Van Hieu, N.T. Hong, Adv. Nat. Sci:Nanosci. Nanotechnol. 7 (2016) 033001. doi: 10.1088/2043-6262/7/3/033001
4. [4]
  Z.J. Gong, C.C. Wang, C. Wang, et al., Analyst 139 (2014) 5283-5289. doi: 10.1039/C4AN00968A
5. [5]
  X.Y. Liu, X.Q. Wang, L.S. Zha, et al., J. Mater. Chem. C 2 (2014) 7326-7335. doi: 10.1039/C4TC00966E
6. [6]
  X. Dong, X.Y. Liu, L.S. Zha, Prog. Chem. 25 (2013) 2038-2052.
7. [7]
  H. Zhang, J.S. Han, B. Yang, Adv. Funct. Mater. 20 (2010) 1533-1550. doi: 10.1002/adfm.201000089
8. [8]
  I. Tokarev, S. Minko, Soft Matter 8 (2012) 5980-5987. doi: 10.1039/c2sm25069a
9. [9]
  D.D. Diaz, D. Kuehbeck, R.J. Koopmans, Chem. Soc. Rev. 40 (2011) 427-448. doi: 10.1039/C005401C
10. [10]
  X.Y. Liu, C. Zhang, J.M. Yang, et al., RSC Adv. 3 (2013) 3384-3390. doi: 10.1039/c3ra22742a
11. [11]
  S.Y. Li, D.L. Lin, J.F. Zhou, L.S. Zha, J. Phys. Chem. C 120 (2016) 4902-4908. doi: 10.1021/acs.jpcc.5b11724
12. [12]
  L.S. Zha, B. Banik, F. Alexis, Soft Matter 7 (2011) 5908-5916. doi: 10.1039/c0sm01307b
13. [13]
  S.G. Cao, B.H. Hu, H.Q. Liu, Polym. Int. 58 (2009) 545-551. doi: 10.1002/pi.2565
14. [14]
  M.A.C. Stuart, W.T.S. Huck, J. Genzer, et al., Nat. Mater. 9 (2010) 101-113. doi: 10.1038/nmat2614
15. [15]
  Y.Y. Liu, X.Y. Liu, J.M. Yang, et al., Colloids and Surfaces A:Physicochem. Eng. Aspects 393 (2012) 105-110. doi: 10.1016/j.colsurfa.2011.11.007
16. [16]
  C.B. Huang, S.J. Soenen, J. Rejman, et al., Chem. Soc. Rev. 40 (2011) 2417-2434. doi: 10.1039/c0cs00181c
17. [17]
  J. Xie, X. Li, Y. Xia, Macromol. Rapid Commun. 29 (2008) 1775-1792. doi: 10.1002/marc.200800381
18. [18]
  X. Jin, Y.L. Hsieh, Polymer 46 (2005) 5149-5160. doi: 10.1016/j.polymer.2005.04.066
19. [19]
  S. Ramakrishna, K. Fujihara, W.E. Teo, et al., Mater. Today 9 (2006) 40-50.
20. [20]
  I.D. Kim, A. Rothschild, B.H. Lee, et al., Nano Lett. 6 (2006) 2009-2013. doi: 10.1021/nl061197h
21. [21]
  D. Li, Y.N. Xia, Adv. Mater. 16 (2004) 1151-1170. doi: 10.1002/adma.200400719
22. [22]
  A. Greiner, J.H. Wendorff, Angew. Chem., Int. Ed. 46 (2007) 5670-5703. doi: 10.1002/anie.200604646
23. [23]
  S.Y. Chen, L.Y. Wang, X. Dong, et al., RSC Adv. 6 (2016) 48479-48488. doi: 10.1039/C6RA04247C
24. [24]
  M. Karg, T. Hellweg, J. Mater. Chem. 19 (2009) 8714-8727. doi: 10.1039/b820292n
25. [25]
  N.S. Satarkar, D. Biswal, J.Z. Hilt, Soft Matter 6 (2010) 2364-2371. doi: 10.1039/b925218p
26. [26]
  Y. Lu, Y. Mei, M. Drechsler, M. Ballauff, Angew. Chem. Int. Ed. 45 (2006) 813-816. doi: 10.1002/anie.200502731
27. [27]
  L.Y. Wang, S.Y. Chen, J.F. Zhou, et al., Macromol. Mater. Eng. 302 (2017) 1700181. doi: 10.1002/mame.201700181
28. [28]
  L.N. Chen, Y.C. Chiu, J.J. Hung, C.C. Kuo, W.C. Chen, Macromol. Chem. Phys. 215 (2014) 286-294. doi: 10.1002/macp.201300604
29. [29]
  D. He, B. Hu, Q.F. Yao, K. Wang, S.H. Yu, ACS Nano 3 (2009) 3993-4002. doi: 10.1021/nn900812f
30. [30]
  G.C. Zheng, L. Polavarapu, L.M. Liz-Marzan, I. Pastoriza-Santos, J. Perez-Juste, Chem. Commun. 51 (2015) 4572-4575. doi: 10.1039/C4CC09466B
31. [31]
  X.Y. Dong, Z.W. Gao, K.F. Yang, W.Q. Zhang, L.W. Xu, Catal. Sci. Technol. 5 (2015) 2554-2574. doi: 10.1039/C5CY00285K
32. [32]
  W. Xie, C. Herrmann, K. Koempe, M. Haase, S. Schluecker, J. Am. Chem. Soc. 133 (2011) 19302-19305. doi: 10.1021/ja208298q
33. [33]
  W. Xie, B. Walkenfort, S. Schluecker, J. Am. Chem. Soc. 135 (2013) 1657-1660. doi: 10.1021/ja309074a
1. [1]
  Guangyao Wang , Zhitong Xu , Ye Qi , Yueguang Fang , Guiling Ning , Junwei Ye . Electrospun nanofibrous membranes with antimicrobial activity for air filtration. Chinese Chemical Letters, 2024, 35(10): 109503-. doi: 10.1016/j.cclet.2024.109503
2. [2]
  Xiujuan Wang , Yijie Wang , Luyun Cui , Wenqiang Gao , Xiao Li , Hong Liu , Weijia Zhou , Jingang Wang . Coordination-based synthesis of Fe single-atom anchored nitrogen-doped carbon nanofibrous membrane for CO₂ electroreduction with nearly 100% CO selectivity. Chinese Chemical Letters, 2024, 35(12): 110031-. doi: 10.1016/j.cclet.2024.110031
3. [3]
  Xinyu Ren , Hong Liu , Jingang Wang , Jiayuan Yu . Electrospinning-derived functional carbon-based materials for energy conversion and storage. Chinese Chemical Letters, 2024, 35(6): 109282-. doi: 10.1016/j.cclet.2023.109282
4. [4]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
5. [5]
  Jiaqi Lin , Pupu Yang , Yimin Jiang , Shiqian Du , Dongcai Zhang , Gen Huang , Jinbo Wang , Jun Wang , Qie Liu , Miaoyu Li , Yujie Wu , Peng Long , Yangyang Zhou , Li Tao , Shuangyin Wang . Surface decoration prompting the decontamination of active sites in high-temperature proton exchange membrane fuel cells. Chinese Chemical Letters, 2024, 35(11): 109435-. doi: 10.1016/j.cclet.2023.109435
6. [6]
  Jisheng Liu , Junli Chen , Xifeng Zhang , Yin Wu , Xin Qi , Jie Wang , Xiang Gao . Red blood cell membrane-coated FLT3 inhibitor nanoparticles to enhance FLT3-ITD acute myeloid leukemia treatment. Chinese Chemical Letters, 2024, 35(9): 109779-. doi: 10.1016/j.cclet.2024.109779
7. [7]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
8. [8]
  Yu Mao , Yilin Liu , Xiaochen Wang , Shengyang Ni , Yi Pan , Yi Wang . Acylfluorination of enynes via phosphine and silver catalysis. Chinese Chemical Letters, 2024, 35(8): 109443-. doi: 10.1016/j.cclet.2023.109443
9. [9]
  Zhichao Zhou , Fuqian Chen , Xiaotong Xia , Dong Ye , Rong Zhou , Lei Li , Tao Deng , Zhenhua Ding , Fang Liu . Developing a fluorescence substrate for HRP-based diagnostic assays with superiorities over the commercial ADHP. Chinese Chemical Letters, 2024, 35(6): 108970-. doi: 10.1016/j.cclet.2023.108970
10. [10]
  Wenya Jiang , Jianyu Wei , Kuan-Guan Liu . Atomically precise superatomic silver nanoclusters stabilized by O-donor ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100371-100371. doi: 10.1016/j.cjsc.2024.100371
11. [11]
  Feihu Wu , Gengwen Chen , Kaitao Lai , Shiqing Zhang , Yingchao Liu , Ruijian Luo , Xiaocong Wang , Pinzhi Cao , Yi Ye , Jiarong Lian , Junle Qu , Zhigang Yang , Xiaojun Peng . Non-specific/specific SERS spectra concatenation for precise bacteria classifications with few samples using a residual neural network. Chinese Chemical Letters, 2025, 36(1): 109884-. doi: 10.1016/j.cclet.2024.109884
12. [12]
  Jianwen Zhao , Shuai Wang , Shanshan Zhao , Liwei Chen , Fangang Meng , Xuelin Tian . A non-fluorinated liquid-like membrane with excellent anti-scaling performance for membrane distillation. Chinese Chemical Letters, 2025, 36(1): 109883-. doi: 10.1016/j.cclet.2024.109883
13. [13]
  Jie Ren , Hao Zong , Yaqun Han , Tianyi Liu , Shufen Zhang , Qiang Xu , Suli Wu . Visual identification of silver ornament by the structural color based on Mie scattering of ZnO spheres. Chinese Chemical Letters, 2024, 35(9): 109350-. doi: 10.1016/j.cclet.2023.109350
14. [14]
  Ya-Wen Zhang , Ming-Ming Gan , Li-Ying Sun , Ying-Feng Han . Supramolecular dinuclear silver(I) and gold(I) tetracarbene metallacycles and fluorescence sensing of penicillamine. Chinese Journal of Structural Chemistry, 2024, 43(9): 100356-100356. doi: 10.1016/j.cjsc.2024.100356
15. [15]
  Ting Pan , Dinghu Zhang , Guomei You , Xiaoxia Wu , Chenguang Zhang , Xinyu Miao , Wenzhi Ren , Yiwei He , Lulu He , Yuanchuan Gong , Jie Lin , Aiguo Wu , Guoliang Shao . PD-L1 targeted iron oxide SERS bioprobe for accurately detecting circulating tumor cells and delineating tumor boundary. Chinese Chemical Letters, 2025, 36(1): 109857-. doi: 10.1016/j.cclet.2024.109857
16. [16]
  Yixin Zhang , Ting Wang , Jixiang Zhang , Pengyu Lu , Neng Shi , Liqiang Zhang , Weiran Zhu , Nongyue He . Formation mechanism for stable system of nanoparticle/protein corona and phospholipid membrane. Chinese Chemical Letters, 2024, 35(4): 108619-. doi: 10.1016/j.cclet.2023.108619
17. [17]
  Shuangying Li , Qingxiang Zhou , Zhi Li , Menghua Liu , Yanhui Li . Sensitive measurement of silver ions in environmental water samples integrating magnetic ion-imprinted solid phase extraction and carbon dot fluorescent sensor. Chinese Chemical Letters, 2024, 35(5): 108693-. doi: 10.1016/j.cclet.2023.108693
18. [18]
  Bharathi Natarajan , Palanisamy Kannan , Longhua Guo . Metallic nanoparticles for visual sensing: Design, mechanism, and application. Chinese Journal of Structural Chemistry, 2024, 43(9): 100349-100349. doi: 10.1016/j.cjsc.2024.100349
19. [19]
  Ying Hou , Zhen Liu , Xiaoyan Liu , Zhiwei Sun , Zenan Wang , Hong Liu , Weijia Zhou . Laser constructed vacancy-rich TiO_2-x/Ti microfiber via enhanced interfacial charge transfer for operando extraction-SERS sensing. Chinese Chemical Letters, 2024, 35(9): 109634-. doi: 10.1016/j.cclet.2024.109634
20. [20]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(568)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142