Citation: Huang Ge, Wang Yue, Liu Tianfu. A low-temperature synthesis-induced defect formation strategy for stable hierarchical porous metal-organic frameworks[J]. Chinese Chemical Letters, ;2019, 30(12): 2309-2312. doi: 10.1016/j.cclet.2019.04.030 shu

A low-temperature synthesis-induced defect formation strategy for stable hierarchical porous metal-organic frameworks

Huang Ge ^a,1 ,
Wang Yue ^b,1, ,
Liu Tianfu ^a,*,

a.
Fujian Institute of Research on the Structure of Matter, State Key Laboratory of Structural Chemistry, Chinese Academy of Sciences, Fuzhou 350002, China
b.
College of Biological and Chemical Engineering, Chongqing University of Education, Chongqing 400067, China

wangyue@cque.edu.cn

tfliu@fjirsm.ac.cn

Received Date: 18 March 2019
Revised Date: 8 April 2019
Accepted Date: 12 April 2019
Available Online: 13 December 2019

Figures(3)

A stable hierarchical porous metal-organic framework PCN-56 with abundant Lewis acid sites (denoted as Defective-PCN-56) was synthesized by the low-temperature synthesis-induced defect formation method. The existence of mesopore in structure was confirmed by N₂ sorption isotherm and the successful encapsulation of large dye molecules. The Defective-PCN-56 has higher loading capacity toward anti-cancer drug Doxo compared with that of "nearly ideal-crystal" (denoted as Ideal-PCN-56) synthesized at high temperature, showing potential application as drug carrier. The low-temperature synthesis-induced defect formation strategy presented here provides a new and facile way to synthesize stable MOFs with the combination of intrinsic micropore and additional mesopore as well as abundant Lewis acid sites.
- Low-temperature induced,
- Defect formation strategy,
- Stable MOFs,
- Hierarchical porous MOFs,
- Lewis acid sites
1. [1]
  L.Liu, Z.B.Han, S.M.Wang, D.Q.Yuan, N.S.Weng, Inorg.Chem.54 (2017)3719-3721.
2. [2]
  N. Wei, Y. Zhang, L. Liu, Z.B. Han, D.Q. Yuan, Appl. Catal. B-Environ. 219 (2017) 603-610. doi: 10.1016/j.apcatb.2017.07.085
3. [3]
  B. Wang, H. Yang, Y.B. Xie, et al., Chin. Chem. Lett. 27 (2016) 502-506. doi: 10.1016/j.cclet.2015.12.034
4. [4]
  X. Zhao, X.H. Bu, T. Wu, et al., Nat. Commun. 4 (2013) 2344-2352. doi: 10.1038/ncomms3344
5. [5]
  P.Z. Li, X.J. Wang, S.Y. Tan, et al., Angew. Chem. Int. Ed. 54 (2015) 12939-12943.
6. [6]
  Q.R. Fang, D.Q. Yuan, J. Sculley, et al., Inorg. Chem. 49 (2010) 11637-11642. doi: 10.1021/ic101935f
7. [7]
  W.M. Xuan, C.F. Zhu, Y. Liu, Y. Cui, Chem. Soc. Rev. 41 (2012) 1677-1695. doi: 10.1039/C1CS15196G
8. [8]
  Y.F. Yue, Z.A. Qiao, P.F. Fulvio, et al., J. Am. Chem. Soc. 135 (2013) 9572-9575. doi: 10.1021/ja402694f
9. [9]
  G.R. Cai, H.L. Jiang, Angew. Chem. Int. Ed. 56 (2017) 563-567. doi: 10.1002/anie.201610914
10. [10]
  H.L. Huang, J.R. Li, K.K. Wang, et al., Nat. Commun. 6 (2015) 8847-8854. doi: 10.1038/ncomms9847
11. [11]
  J. Reboul, S. Furukawa, N. Horike, et al., Nat. Mater. 11 (2012) 717-723. doi: 10.1038/nmat3359
12. [12]
  L.G. Qiu, T. Xu, Z.Q. Li, et al., Angew. Chem. Int. Ed. 47 (2008) 9487-9491. doi: 10.1002/anie.200803640
13. [13]
  G.C. Shearer, S. Chavan, J. Ethiraj, et al., Chem. Mater. 26 (2014) 4068-4071. doi: 10.1021/cm501859p
14. [14]
  M.R. DeStefano, T. Islamoglu, S.J. Garibay, J.T. Hupp, O.K. Farha, Chem. Mater. 29 (2017) 1357-1361. doi: 10.1021/acs.chemmater.6b05115
15. [15]
  J. Canivet, M. Vandichel, D. Farrusseng, Dalton Trans. 45 (2016) 4090-4099. doi: 10.1039/C5DT03522H
16. [16]
  Z.L. Fang, B. Bueken, D.E.D. Vos, R.A. Fischer, Angew. Chem. Int. Ed. 54 (2015) 7234-7254. doi: 10.1002/anie.201411540
17. [17]
  J.S. Choi, W.J. Son, J. Kim, W.S. Ahn, Microporous Mesoporous Mater.116 (2008) 727-731. doi: 10.1016/j.micromeso.2008.04.033
18. [18]
  H.Wu, Y.S.Chua, V.Krungleviciute, etal., J.Am.Chem.Soc.135 (2013)10525-10532. doi: 10.1021/ja404514r
19. [19]
  F. Vermoortele, M. Vandichel, B.V.D. Voorde, et al., Angew. Chem. Int. Ed. 51 (2012) 4887-4890. doi: 10.1002/anie.201108565
20. [20]
  L. Valenzano, B. Civalleri, S. Chavan, et al., Chem. Mater. 23 (2011) 1700-1718. doi: 10.1021/cm1022882
21. [21]
  S.H. Yang, X. Lin, W. Lewis, et al., Nat. Mater. 11 (2012) 710-716. doi: 10.1038/nmat3343
22. [22]
  F.X.L.I. Xamena, F.G. Cirujano, A. Corma, Microporous Mesoporous Mater. 157 (2012) 112-117. doi: 10.1016/j.micromeso.2011.12.058
23. [23]
  J.H. Cavka, S. Jakobsen, U. Olsbye, et al., J. Am. Chem. Soc. 130 (2008) 13850-13851. doi: 10.1021/ja8057953
24. [24]
  V. Bon, I. Senkovska, M.S. Weiss, S. Kaskel, CrystEngComm 15 (2013) 9572-9577. doi: 10.1039/c3ce41121d
25. [25]
  H.L. Jiang, D.W. Feng, T.F. Liu, J.R. Li, H.C. Zhou, J. Am. Chem. Soc. 134 (2012) 14690-14693. doi: 10.1021/ja3063919
26. [26]
  K. Koh, A.G. Wong-Foy, A.J. Matzger, J. Am. Chem. Soc. 131 (2009) 4184-4185. doi: 10.1021/ja809985t
27. [27]
  J. An, S.J. Geib, N.L. Rosi, J. Am. Chem. Soc. 132 (2010) 38-39. doi: 10.1021/ja909169x
28. [28]
  J.S. Oliveira, R. Montalvao, L. Daher, P.A.Z. Suarez, J.C. Rubim, Talanta 69 (2006) 1278-1284. doi: 10.1016/j.talanta.2006.01.002
29. [29]
  T. Devic, C. Serre, Chem. Soc. Rev. 43 (2014) 6097-6115. doi: 10.1039/C4CS00081A
30. [30]
  G. Férey, C. Mellot-Draznieks, C. Serre, et al., Science 309 (2005) 2040-2042. doi: 10.1126/science.1116275
31. [31]
  N.M. Padial, E.Q. Procopio, C. Montoro, et al., Angew. Chem. Int. Ed. 52 (2013) 8290-8294. doi: 10.1002/anie.201303484
32. [32]
  D.W. Feng, Z.Y. Gu, J.R. Li, et al., Angew. Chem. Int. Ed. 51 (2012) 10307-10310. doi: 10.1002/anie.201204475
33. [33]
  Q. Yang, B. Wang, Y. Chen, Y.B. Xie, J.R. Li, Chin. Chem. Lett. 30 (2019) 234-238. doi: 10.1016/j.cclet.2018.03.023
34. [34]
  Q. Yin, Z. Peng, R.J. Sa, et al., Angew. Chem. Int. Ed. 57 (2018) 7691-7696. doi: 10.1002/anie.201800354
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