Citation: Lu Fan, Yang Jie, Zhou Ling, Wang Xinyue, Yang Yin, Li Jumei. Enhanced electrochemical performance and mechanism study of AgLi_1/3Sn_2/3O₂ for lithium storage[J]. Chinese Chemical Letters, ;2019, 30(12): 2017-2020. doi: 10.1016/j.cclet.2019.04.019 shu

Enhanced electrochemical performance and mechanism study of AgLi_1/3Sn_2/3O₂ for lithium storage

Lu Fan ^a,b ,
Yang Jie ^a ,
Zhou Ling ^a ,
Wang Xinyue ^a ,
Yang Yin ^b ,
Li Jumei ^a,*,

a.
School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430205, China
b.
Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816, China

jumeili2006@163.com

Received Date: 25 January 2019
Revised Date: 27 March 2019
Accepted Date: 9 April 2019
Available Online: 10 December 2019

Figures(4)

Herein, AgLi_1/3Sn_2/3O₂ with delafossite structure was prepared by treating the layered compound Li₂SnO₃ with molten AgNO₃ via ion exchange of Li⁺ for Ag⁺. The structure characterization and the electrochemical performance of AgLi_1/3Sn_2/3O₂ was thoroughly investigated. AgLi_1/3Sn_2/3O₂ is found to possess stacking lamellar morphology, which means small electrochemical impedance and so facilitates charge transfer kinetics during the cycling. Compared with Li₂SnO₃, due to the introducing of excellent electrical conductivity of silver, AgLi_1/3Sn_2/3O₂ exhibits improved electrochemical performance in terms of capacity, cycling stability and coulombic efficiency. The results show AgLi_1/3Sn_2/3O₂ presents favorable specific capacity of 339 mAh/g at current density of 200 mA/g after 50 cycles and initial coulombic efficiency of 96%. Ex situ XRD analysis revealed the reaction mechanism of AgLi_1/3Sn_2/3O₂ as an anode for lithium ion batteries.
- Lithium ion battery,
- AgLi_1/3Sn_2/3O₂,
- Delafossite structure,
- Charge transfer kinetics,
- Reaction mechanism
1. [1]
  M. Armand, J.M. Tarascon, Nature 451 (2008) 652-657. doi: 10.1038/451652a
2. [2]
  B. Dunn, H. Kamath, J.M. Tarascon, Science 334 (2011) 928-935. doi: 10.1126/science.1212741
3. [3]
  H. Yuan, L. Kong, T. Li, et al., Chin. Chem. Lett. 28 (2017) 2180-2194. doi: 10.1016/j.cclet.2017.11.038
4. [4]
  M. Hong, J. Li, W. Zhang, Q. Zhang, Energy Fuels 32 (2018) 6371-6377. doi: 10.1021/acs.energyfuels.8b00454
5. [5]
  F. Lu, S.Z. Liu, G.F. Zeng, J.M. Li, Y. Yang, J. Electrochem. Soc. 165 (2018) A2897-A2903. doi: 10.1149/2.0201811jes
6. [6]
  L. Hao, L. Long, P. Kunal, et al., J. Phys. Chem. C 122 (2018) 2712-2716. doi: 10.1021/acs.jpcc.7b10974
7. [7]
  S.L. Yang, B.H. Zhou, M. Lei, et al., Chin. Chem. Lett. 26 (2015) 1293-1297. doi: 10.1016/j.cclet.2015.05.051
8. [8]
  Z. Zhang, Y. Hou, S. Zhang, et al., Chin. Chem. Lett. 29 (2018) 1656-1660. doi: 10.1016/j.cclet.2018.06.017
9. [9]
  M.V. Reddy, G.V. Subba Rao, B.V. Chowdari, Chem. Rev. 113 (2013) 5364-5457. doi: 10.1021/cr3001884
10. [10]
  Q.F. Wang, Y. Huang, J. Miao, Y. Wang, Y. Zhao, Appl. Surf. Sci. 258 (2012) 6923-6929. doi: 10.1016/j.apsusc.2012.03.136
11. [11]
  Y. Zhao, Y. Huang, Q. Wang, et al., J. Appl. Electrochem. 43 (2013) 1243-1248. doi: 10.1007/s10800-013-0612-8
12. [12]
  Q.F. Wang, S. Yang, J. Miao, et al., Appl. Surf. Sci. 469 (2019) 253-261. doi: 10.1016/j.apsusc.2018.11.055
13. [13]
  D.W. Zhang, S.Q. Zhang, Y. Jin, et al., J. Alloys Compd. 415 (2006) 229-233. doi: 10.1016/j.jallcom.2005.05.053
14. [14]
  S.H. Huang, Z.Y. Wen, X.J. Zhu, Z.H. Gu, Electrochem. Commun. 6 (2004) 1093-1097. doi: 10.1016/j.elecom.2004.08.013
15. [15]
  J.Y. He, W.M. Wang, Z.G. Zou, F. Long, Z.Y. Fu, Ionics 20 (2014) 1063-1070. doi: 10.1007/s11581-013-1049-0
16. [16]
  H.Q. Tang, Z.Y. Tang, C.Q. Du, F.C. Qie, J.T. Zhu, Electrochim. Acta 120 (2014) 187-192. doi: 10.1016/j.electacta.2013.12.090
17. [17]
  Y. Hosogi, H. Kato, A. Kudo, J. Mater. Chem. 18 (2008) 647-653. doi: 10.1039/B715679K
18. [18]
  D.R. Shannon, Acta Crystallogr. Sect. A 32 (1976) 751-767. doi: 10.1107/S0567739476001551
19. [19]
  J. Bréger, M. Jiang, N. Dupré, et al., J. Solid State Chem. 178 (2005) 2575-2585. doi: 10.1016/j.jssc.2005.05.027
20. [20]
  B. Mortemard de Boisse, G. Liu, J. Ma, et al., Nat. Commun. 7 (2016) 11397. doi: 10.1038/ncomms11397
21. [21]
  Y. Masatomo, I. Mitsuru, I. Yoshiyuki, M. Yukio, J. Am. Chem. Soc. 127 (2005) 3491-3495. doi: 10.1021/ja0449224
22. [22]
  L. Weng, J. Zhou, R. Cai, Int. J. Mech. Sci. 141 (2018) 245-161. doi: 10.1016/j.ijmecsci.2018.04.013
23. [23]
  I.A. Courtney, J. Electrochem. Soc. 144 (1997) 2045-2052. doi: 10.1149/1.1837740
24. [24]
  W. Dong, J. Xu, C. Wang, et al., Adv. Mater. 29 (2017) 1700136. doi: 10.1002/adma.201700136
25. [25]
  F. Belliard, J.T.S. Irvine, Ionics 7 (2001) 16-21. doi: 10.1007/BF02375462
1. [1]
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2. [2]
  Qin Cheng , Ming Huang , Qingqing Ye , Bangwei Deng , Fan Dong . Indium-based electrocatalysts for CO₂ reduction to C1 products. Chinese Chemical Letters, 2024, 35(6): 109112-. doi: 10.1016/j.cclet.2023.109112
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5. [5]
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6. [6]
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7. [7]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
8. [8]
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9. [9]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
10. [10]
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11. [11]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
12. [12]
  Yi Herng Chan , Zhe Phak Chan , Serene Sow Mun Lock , Chung Loong Yiin , Shin Ying Foong , Mee Kee Wong , Muhammad Anwar Ishak , Ven Chian Quek , Shengbo Ge , Su Shiung Lam . Thermal pyrolysis conversion of methane to hydrogen (H₂): A review on process parameters, reaction kinetics and techno-economic analysis. Chinese Chemical Letters, 2024, 35(8): 109329-. doi: 10.1016/j.cclet.2023.109329
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16. [16]
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17. [17]
  Yong Wang , Yingying Zhao , Boshun Wan . Analysis of Organic Questions in the 37th Chinese Chemistry Olympiad (Preliminary). University Chemistry, 2024, 39(11): 406-416. doi: 10.12461/PKU.DXHX202403009
18. [18]
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19. [19]
  Chang Liu , Zirui Song , Xinglan Deng , Shihong Xu , Renji Zheng , Wentao Deng , Hongshuai Hou , Guoqiang Zou , Xiaobo Ji . Interfacial/bulk synergetic effects accelerating charge transferring for advanced lithium-ion capacitors. Chinese Chemical Letters, 2024, 35(6): 109081-. doi: 10.1016/j.cclet.2023.109081
20. [20]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038

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沈阳化工大学材料科学与工程学院沈阳 110142

Enhanced electrochemical performance and mechanism study of AgLi1/3Sn2/3O2 for lithium storage

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通讯作者: 陈斌, bchen63@163.com

Enhanced electrochemical performance and mechanism study of AgLi_1/3Sn_2/3O₂ for lithium storage