Citation: Lin Xiaoyun, Wang Yanfang, Zou Miaomiao, Lan Tianxiang, Ni Yongnian. Electrochemical non-enzymatic glucose sensors based on nano-composite of Co₃O₄ and multiwalled carbon nanotube[J]. Chinese Chemical Letters, ;2019, 30(6): 1157-1160. doi: 10.1016/j.cclet.2019.04.009 shu

Electrochemical non-enzymatic glucose sensors based on nano-composite of Co₃O₄ and multiwalled carbon nanotube

a.
College of Chemistry, Nanchang University, Nanchang 330031, China
b.
State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang 330047, China

linxiaoyun@ncu.edu.cn

Received Date: 31 December 2018
Revised Date: 31 March 2019
Accepted Date: 3 April 2019
Available Online: 3 June 2019

Figures(4)

Nanocomposite of Co₃O₄ and multiwalled carbon nanotube (MCNT) was synthesised using one step solvothermal method, and an electrochemical non-enzymatic glucose sensor (Co₃O₄-MCNT/GCE) was successfully constructed by a dropping method. The obtained Co₃O₄ and Co₃O_4^- MCNT were characterized and investigated by transmission electron microscopy (TEM) and energy dispersive Xray spectroscopy (EDS). Quantitative analysis of glucose was performed using the amperometric (i-t) method, and plot of current difference versus concentration of glucose was linear in the range of 1.0-122 μmol/L, with a linear correlation coefficient (R²) of 0.9983 and limit of detection (LOD) of 0.28 μmol/L. Sensitivity of this sensor was evaluated as 2550 μA L mmol^-1 cm^-2. This new sensor produced satisfactory reproducibility and stability and was applied to monitor trace amounts of glucose in human serum samples.
- Nanocomposite,
- Co₃O₄,
- Multiwalled carbon nanotube (MCNT),
- Non-enzymatic glucose sensors,
- Serum sample
1. [1]
  G. Yong, Y.G. Zhang, J.Y. Ying, Angew. Chem. Int. Ed. 47(2008) 9345-9348. doi: 10.1002/anie.200803207
2. [2]
  H.F. Bunn, P.J. Higgins, Science 231(1981) 222-224.
3. [3]
  J. Xu, C.L. Bartolome, C.S. Low, et al., Nature 556(2018) 505. doi: 10.1038/s41586-018-0049-7
4. [4]
  Y.F. Xiao, H. Sung, J.Z. Du, J. Am. Chem. Soc. 139(2017) 7640-7647. doi: 10.1021/jacs.7b03219
5. [5]
  S.Z. Swidan, P.A. Montgomery, Pharmacotherapy 18(1998) 961-972.
6. [6]
  A. Whaley-Connell, J.R. Sowers, Diabetes 63(2014) 45-47. doi: 10.2337/db13-1497
7. [7]
  M. Gu, J.W. Wang, Y.F. Tu, J.W. Di, Sens. Actuators B:Chem.148(2010) 486-491. doi: 10.1016/j.snb.2010.05.057
8. [8]
  L. Mauko, B. Ogorevc, B. Pihlar, Electroanalysis 21(2009) 2535-2541. doi: 10.1002/elan.v21:23
9. [9]
  J.H. Kim, S.A. Jun, Y. Kwon, et al., Bioelectrochemistry 101(2015) 114-119. doi: 10.1016/j.bioelechem.2014.08.017
10. [10]
  M. Xiong, B. Gu, J.D. Zhang, et al., Biosen. Bioelectron. 50(2013) 229-234. doi: 10.1016/j.bios.2013.06.030
11. [11]
  R. Wilson, A.P.F. Turner, Biosens. Bioelectron. 7(1992) 165-185. doi: 10.1016/0956-5663(92)87013-F
12. [12]
  C.M. Wong, K.H. Wong, X.D. Chen, Appl. Microbiol. Biotechnol. 78(2008) 927-938. doi: 10.1007/s00253-008-1407-4
13. [13]
  Y. Liu, C.M. Deng, L. Tang, et al., J. Am. Chem. Soc. 133(2011) 660-663. doi: 10.1021/ja107086y
14. [14]
  S.A. Zaidi, J.H. Shin, Talanta 149(2016) 30-42. doi: 10.1016/j.talanta.2015.11.033
15. [15]
  Q.Y. Liu, P.P. Chen, Z. Xu, et al., Sens. Actuators B:Chem. 251(2017) 339-348. doi: 10.1016/j.snb.2017.05.069
16. [16]
  Y. Su, H. Guo, Z.S. Wang, et al., Sens. Actuators B:Chem. 255(2018) 2510-2519. doi: 10.1016/j.snb.2017.09.056
17. [17]
  A.C. Pradhan, T. Uyar, ACS Appl. Mater. Interfaces 41(2017) 35757-35774.
18. [18]
  H. Pang, X.R. Li, Q.X. Zhao, et al., Nano Energy 35(2017) 138-145. doi: 10.1016/j.nanoen.2017.02.044
19. [19]
  M. Huang, Y.X. Zhang, F. Li, et al., J. Power Sources 252(2014) 98-106. doi: 10.1016/j.jpowsour.2013.12.030
20. [20]
  J. Xu, Q.F. Wang, X.W. Wang, et al., ACS Nano 7(2013) 5453-5462. doi: 10.1021/nn401450s
21. [21]
  D. Gu, W. Li, F. Wang, et al., Agnew. Chem. Int. Ed. 54(2015) 7060-7064. doi: 10.1002/anie.201501475
22. [22]
  X. Li, X.D. Tian, T. Yang, Y. Song, Z.J. Liu, Chem. -Eur. J. 24(2018) 14477-14483. doi: 10.1002/chem.201802715
23. [23]
  X.W. Wang, F.X. Wang, L.Y. Wang, et al., Adv. Mater. 28(2016) 4904-4911. doi: 10.1002/adma.v28.24
24. [24]
  H.Y. Xu, C.K. Xia, S.Y. Wang, et al., Sens. Actuators B:Chem. 267(2018) 93-103. doi: 10.1016/j.snb.2018.04.023
25. [25]
  V. Datsyuk, M. Kalyva, K. Papagelis, et al., Carbon 46(2018) 833-840.
26. [26]
  G.C. Yu, M. Xue, Z.B. Zhang, et al., J. Am. Chem. Soc. 134(2012) 13248-13251. doi: 10.1021/ja306399f
27. [27]
  X.W. Wang, M.X. Li, Z. Chang, et al., ACS Appl. Mater. Interfaces 7(2015) 2280-2285. doi: 10.1021/am5062272
28. [28]
  X.Y. Lin, Y.F. Wang, W.H. He, Y.N. Ni, S. Kokot, RSC Adv. 7(2017) 55460-55467.
29. [29]
  L. Wang, Q.Y. Zhang, S.L. Chen, et al., Anal. Chem. 86(2014) 1414-1421. doi: 10.1021/ac401563m
30. [30]
  K.E. Toghill, R.G. Compton, Int. J. Electrochem. Sci. 5(2010) 1246-1301.
31. [31]
  X. Zhong, R. Yuan, Y.Q. Chai, Chem. Commun. 48(2012) 597-599. doi: 10.1039/C1CC16081H
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Electrochemical non-enzymatic glucose sensors based on nano-composite of Co3O4 and multiwalled carbon nanotube

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通讯作者: 陈斌, bchen63@163.com

Electrochemical non-enzymatic glucose sensors based on nano-composite of Co₃O₄ and multiwalled carbon nanotube