Citation: Sun Qi, Liu Liyan, Yang Yu, Zha Zhenggen, Wang Zhiyong. Unexpected activated carbon-catalyzed pyrrolo[1, 2-a]quinoxalines synthesis in water[J]. Chinese Chemical Letters, ;2019, 30(7): 1379-1382. doi: 10.1016/j.cclet.2019.04.007 shu

Unexpected activated carbon-catalyzed pyrrolo[1, 2-a]quinoxalines synthesis in water

Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry & Center for Excellence in Molecular Synthesis of Chinese Academy of Sciences, Collaborative Innovation Center of Suzhou Nano Science and Technology & School of Chemistry and Materials Science in University of Science and Technology of China, Hefei 230026, China

zwang3@ustc.edu.cn

Received Date: 28 January 2019
Revised Date: 6 March 2019
Accepted Date: 3 April 2019
Available Online: 3 July 2019

Figures(3)

An interesting and recyclable activated carbon/water catalytic system for efficient synthesis of pyrrolo[1, 2-a]quinoxaline derivatives was developed. The intramolecular C-N and C-C bond can be easily constructed in water under mild condition. This reaction features a broad substrate scope, a good tolerance to water and air, metal-free, additive-free and redox reagent-free.
- Pyrrolo[1, 2-a]quinoxalines,
- Activated carbon,
- C-C C-N bond-forming,
- Metal free,
- Water solvent
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