Citation: Wang Qinqin, Zhu Mingyuan, Dai Bin, Zhang Jinli. A novel and effective Zn/PEI-MCM catalyst for the acetylene hydration to acetaldehyde[J]. Chinese Chemical Letters, ;2019, 30(6): 1244-1248. doi: 10.1016/j.cclet.2019.03.049 shu

A novel and effective Zn/PEI-MCM catalyst for the acetylene hydration to acetaldehyde

Wang Qinqin ^a ,
Zhu Mingyuan ^b,c ,
Dai Bin ^b,c,*, ,
Zhang Jinli ^a,*,

a.
school of Chemical Engineering & Technology, Tianjin University, Tianjin 300350, China
b.
Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi 832000, China
c.
School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, China

E-mail addresses:

db_tea@shzu.edu.cn

zhangjinli@tju.edu.cn

Received Date: 23 January 2019
Revised Date: 28 February 2019
Accepted Date: 27 March 2019
Available Online: 28 June 2019

Figures(9)

MCM-41 material was modified by polyethyleneimine (PEI) using ultrasonic assisted impregnation method with different PEI loading (P-MCM-x, x=0-15 wt%). The synthesised P-MCM-x materials and corresponding Zn/P-MCM-x catalysts were characterised by FTIR, XRD, TEM, BET, XPS, TG and H₂-TPR, as well as their catalytic performance in the hydration of acetylene was investigated. The results showed that the modified materials retained the mesoporous structure with good thermostability, and the corresponding Zn/P-MCM-x displayed the higher catalytic performance than that of Zn/MCM-41 catalyst, especially for the Zn/P-MCM-12 catalyst with about 88% C₂H₂ conversion and 85% selectivity, and the optimal content of PEI is 12 wt%. More importantly, the introduction of PEI enhanced metal-support interaction to make the better metal dispersion and more active sites, and the charge transfer from N atom to Zn species. These all would be responsible for the high activity of the modified Zn catalysts in the acetylene hydration.
- Polyethyleneimine,
- Modified MCM-41,
- Acetylene hydration,
- Zinc catalyst,
- High activity
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