Citation: Zhang Yinli, Sun Kai, Lv Qiyan, Chen Xiaolan, Qu Lingbo, Yu Bing. Recent applications of radical cascade reaction in the synthesis of functionalized 1-indenones[J]. Chinese Chemical Letters, ;2019, 30(7): 1361-1368. doi: 10.1016/j.cclet.2019.03.034 shu

Recent applications of radical cascade reaction in the synthesis of functionalized 1-indenones

Zhang Yinli ^a,1 ,
Sun Kai ^a,1 ,
Lv Qiyan ^a,b ,
Chen Xiaolan ^a,*, ,
Qu Lingbo ^a ,
Yu Bing ^a,b,*,

a.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China
b.
Henan Nonferrous Metals Geological Exploration Institute, Zhengzhou 450052, China

Author Bio:

Xiao-Lan Chen received her PhD degree under the supervision of Prof. Yu-Fen Zhao at Zhengzhou University. She had worked as a researcher in University of Reading and visiting scholar at University of Southern California before joining Zhengzhou University in 2004. Her research interest is developing highly efficient methodologies for the synthesis of P-, S-, F-containing organic compounds

Bing Yu received Bachelor's degree (2009) from Central China Normal University, China, and obtained his pH.D. (2014) under the supervision of Prof. Liang-Nian He at Nankai University, China. He then moved to Beijing Institute of Technology (2014–2016), Seoul National University (2015–2016) and Tokyo Institute of Technology (2016–2017) as a postdoctoral researcher. He joined Zhengzhou University in 2017. His research interest is developing novel approaches for green and efficient organic synthesis

chenxl@zzu.edu.cn

bingyu@zzu.edu.cn

Received Date: 13 February 2019
Revised Date: 18 March 2019
Accepted Date: 19 March 2019
Available Online: 22 July 2019

Figures(18)

1-Indenones are important scaffolds in natural products, biologically active molecules as well as functional materials. Recently, radical cascade cyclization has emerged as an efficient and powerful strategy for the construction of valuable and versatile functionalized 1-indenones. In this review, the recent advances of this rapidly growing area were summarized. The selected examples have been classified according to the type of reaction substrates such as 1, 3-diarylpropynones, 2-alkynylbenzonitriles, arylpropynols, 1, 5-enynes and 2-alkynylated bromocinnamates.
- Radical cascade reaction,
- 1, 3-Diarylpropynones,
- 2-Alkynylbenzonitriles,
- Arylpropynols,
- 1-Indenones
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