Citation: Zhao Chang-Xin, Li Bo-Quan, Liu Jia-Ning, Huang Jia-Qi, Zhang Qiang. Transition metal coordinated framework porphyrin for electrocatalytic oxygen reduction[J]. Chinese Chemical Letters, ;2019, 30(4): 911-914. doi: 10.1016/j.cclet.2019.03.026 shu

Transition metal coordinated framework porphyrin for electrocatalytic oxygen reduction

a.
Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
b.
Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China

zhang-qiang@mails.tsinghua.edu.cn

Received Date: 7 March 2019
Revised Date: 13 March 2019
Accepted Date: 15 March 2019
Available Online: 19 April 2019

Figures(3)

Oxygen reduction reaction (ORR) constitutes the core process of many clean and sustainable energy systems including fuel cells and metal-air batteries. Developing high-performance and cost-efficiency ORR electrocatalysts is of great significance to the practical applications of the above-mentioned energy storage devices. Transition metal coordinated porphyrin electrocatalysts are highly considered as a promising substitution of noble-metal-based electrocatalyst because of their high ORR reactivity, where the ORR performances of the porphyrin-based electrocatalysts are highly dependent on the transition metal center. Herein a series of framework porphyrin electrocatalysts coordinated with different transition metal centers (M-POF, where M is Mn, Fe, Co, Ni, Cu, or Zn) was designed, synthesized, and evaluated in regards of electrocatalytic ORR performances. Among all, the Co-POF electrocatalyst exhibits the best ORR performances with the highest half-wave potential of 0.81 V vs. RHE and the lowest Tafel slope of 53 mV/dec. This contribution affords an optimized high-performance ORR electrocatalyst and provides instructions for further rational design of porphyrin-based ORR electrocatalysts for sustainable energy applications.
- Electrocatalysis,
- Oxygen reduction reaction,
- Transition metal coordination,
- Framework porphyrin,
- Fuel cells
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