Citation: Miao Ling, Qian Xiaoyu, Zhu Dazhang, Chen Ting, Ping Guchuan, Lv Yaokang, Xiong Wei, Liu Yafei, Gan Lihua, Liu Mingxian. From interpenetrating polymer networks to hierarchical porous carbons for advanced supercapacitor electrodes[J]. Chinese Chemical Letters, ;2019, 30(7): 1445-1449. doi: 10.1016/j.cclet.2019.03.010 shu

From interpenetrating polymer networks to hierarchical porous carbons for advanced supercapacitor electrodes

Miao Ling ^a,1 ,
Qian Xiaoyu ^a,1 ,
Zhu Dazhang ^a,*, ,
Chen Ting ^a ,
Ping Guchuan ^a ,
Lv Yaokang ^b ,
Xiong Wei ^c ,
Liu Yafei ^a ,
Gan Lihua ^a ,
Liu Mingxian ^a,*,

a.
Shanghai Key Lab of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China
b.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
c.
School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430073, China

zhudz@tongji.edu.cn

liumx@tongji.edu.cn

Received Date: 17 January 2019
Revised Date: 20 February 2019
Accepted Date: 5 March 2019
Available Online: 6 July 2019

Figures(4)

Hierarchical porous carbons (HPCs) are obtained via in-situ activation of interpenetrating polymer networks (IPNs) obtained from simultaneous polymerization of resorcinol/formaldehyde (R/F) and polyacrylamide (PAM). The hierarchically micro-, meso-and macroporous structure of as-prepared HPCs is attributed to the synergistic pore-forming effect of PAM and KOH, including PAM decomposition, KOH chemical activation, and a foaming process of potassium polyacrylate formed by partial hydrolysis of PAM in KOH aqueous solution. The typical HPC electrode with the highest surface area (2544 m²/g) shows a high specific capacitance of 261 F/g at 1.0 A/g and a superior rate capability of 216 F/g at 20 A/g in alkaline electrolyte. Moreover, the electrode maintains the capacitance retention of 90.8% after 10000 chargingdischarging cycles at 1.0 A/g, exhibiting long cycling life. This study highlights a new avenue towards IPNs-derived carbons with unique pore structure for promising electrochemical applications.
- Hierarchical porous carbon,
- Interpenetrating polymer networks,
- In-situ activation,
- Supercapacitor,
- Electrode
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