Citation: Wang Chengfei, Zhang Wei, Li Wenwu, Zhang Yuanyuan, Tang Xiaodong, Hu Ming. Magnetism tuned by intercalation of various metal ions in coordination polymer[J]. Chinese Chemical Letters, ;2019, 30(7): 1390-1392. doi: 10.1016/j.cclet.2019.03.007 shu

Magnetism tuned by intercalation of various metal ions in coordination polymer

State Key Laboratory of Precision Spectroscopy, Key Laboratory of Polar Materials and Devices(MOE), School of Physics and Materials Science, East China Normal University, Shanghai 200241, China

wwli@ee.ecnu.edu.cn

yyzhang@ee.ecnu.edu.cn

mhu@phy.ecnu.edu.cn

Received Date: 30 January 2019
Revised Date: 27 February 2019
Accepted Date: 4 March 2019
Available Online: 5 July 2019

Figures(3)

Incorporation of guest ions into porous frameworks changed magnetism of the host materials significantly. However, in most cases, the guest ions were monovalent due to lack of reliable method to insert divalent and trivalent guest ions. In this work, we demonstrated that divalent and trivalent metal ions could be inserted into frameworks of a coordinate polymer, Cu₃[Fe(CN)₆]₂, through electrochemical intercalation. The magnetism of the host frameworks was changed among paramagnetic, superparamagnetic, and ferromagnetic as demonstrated by physical property measurement system (PPMS). Furthermore, the magnetization of the frameworks under low temperatures correlated to the guest ions significantly. The ionic radius and net charge of the guest ions influenced the intercalation amount of the guest ions, therefore affected the valence change of Fe³⁺ ions in the host frameworks, finally leading to variation of the magnetism of the host materials.
- Electrochemistry,
- Magnetism,
- Guest ions,
- Prussian Blue analogues
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