Citation: Du Juan, Liu Lei, Yu Yifeng, Zhang Yue, Chen Aibing. "Dissolution-reassembly" for N-doped hollow micro/meso-carbon spheres with high supercapacitor performance[J]. Chinese Chemical Letters, ;2019, 30(7): 1423-1427. doi: 10.1016/j.cclet.2019.03.004 shu

"Dissolution-reassembly" for N-doped hollow micro/meso-carbon spheres with high supercapacitor performance

College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China

chen_ab@163.com

Received Date: 28 January 2019
Revised Date: 28 February 2019
Accepted Date: 4 March 2019
Available Online: 5 July 2019

Figures(4)

Herein, we report a "dissolution-reassembly" approach for preparation of N-doped hollow carbon spheres with mesoporous/microporous composite structure (H(Micro/Meso)CS). Basing on the compositional inhomogeneity inside the nanospheres of 3-aminophenol/formaldehyde (3-AF) polymerization, the internal 3-AF oligomer with low-molecular-weight is dissolved by acetone to form cavity. Then the dispersive 3-AF oligomer reassemble with silica oligomer as pore-forming agent and cetyltrimethyl-ammonium bromide as surfactant to form a mesoporous outer shell. In addition, the amount of acetone has a great influence on the morphology and structure of H(Micro/Meso)CS. The obtained H(Micro/Meso)CS shows uniform spherical and microporous/mesoporous shell structure and has a high specific capacity and excellent high rate capability.
- Issolution-reassembly,
- Hollow micro/meso-carbon spheres,
- Supercapacitor,
- Oligomer,
- Low-molecular-weight
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