Citation: Ning Fandi, Shen Yangbin, Bai Chuang, Wei Jun, Lu Guanbin, Cui Yi, Zhou Xiaochun. Critical importance of current collector property to the performance of flexible electrochemical power sources[J]. Chinese Chemical Letters, ;2019, 30(6): 1282-1288. doi: 10.1016/j.cclet.2019.02.032 shu

Critical importance of current collector property to the performance of flexible electrochemical power sources

Ning Fandi ^a,b ,
Shen Yangbin ^b ,
Bai Chuang ^a,b ,
Wei Jun ^a,b ,
Lu Guanbin ^b ,
Cui Yi ^a,d, ,
Zhou Xiaochun ^a,b,c,

a.
Nano Science and Technology Institute, University of Science and Technology of China, Suzhou 215123, China
b.
Division of Advanced Nanomaterials, Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences(CAS), Suzhou 215123, China
c.
Division of Nanomaterials, Suzhou Institute of Nano-Tech and Nano-Bionics, Nanchang, Chinese Academy of Sciences(CAS), Nanchang 330200, China
d.
Vacuum Interconnected Workstation, Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences(CAS), Suzhou 215123, China

Received Date: 24 December 2018
Revised Date: 17 January 2019
Accepted Date: 28 February 2019
Available Online: 28 June 2019

Figures(4)

Flexible electrochemical power sources are attracting increasing attentions for their unique advantages like flexibility, shape diversity, light weight and excellent mechanical properties. In this research, we discover that the current collector can dramatically affect the performance of flexible electrochemical power sources with large size. For flexible air-breathing proton exchange membrane fuel cell (PEMFC), the performance could have more than 8 times increase by only adjusting the directions of current collectors. The different performances of different current collection types are mainly attributed to the diverse lengths of the electron transfer pathways. In addition, the conductivity of current collector can dramatically affect the capability of flexible PEMFCs with large-size. The flexible PEMFCs with thicker carbon nanotube membrane as current collector (low electric resistance) show higher ability. A mathematic model is successfully built in this work to further understand the performance. Moreover, the model and simulation are also applicable to other flexible power sources, such as flexible Li-ion battery and supercapacitor.
- Flexible,
- Fuel cell,
- CNT membrane,
- Current collector,
- Li-ion battery,
- Supercapacitor,
- Large-size
1. [1]
  P.H. Yang, W.J. Mai, Nano Energy 8(2014) 274-290. doi: 10.1016/j.nanoen.2014.05.022
2. [2]
  X.H. Lu, M.H. Yu, G.M. Wang, Y.X. Tong, Y. Li, Energy Environ. Sci. 7(2014) 2160-2181. doi: 10.1039/c4ee00960f
3. [3]
  D. Langley, G. Giusti, C. Mayousse, et al., Nanotechnology 24(2013) 452001. doi: 10.1088/0957-4484/24/45/452001
4. [4]
  X.F. Wang, X.H. Lu, B. Liu, et al., Adv. Mater. 26(2014) 4763-4782. doi: 10.1002/adma.v26.28
5. [5]
  W. Zeng, L. Shu, Q. Li, et al., Adv. Mater. 26(2014) 5310-5336. doi: 10.1002/adma.201400633
6. [6]
  F.C. Krebs, S.A. Gevorgyan, J. Alstrup, J. Mater. Chem. 19(2009) 5442-5451. doi: 10.1039/b823001c
7. [7]
  L. Nyholm, G. Nystrom, A. Mihranyan, M. Stromme, Adv. Mater. 23(2011) 3751-3769.
8. [8]
  X. Wang, Z. Li, W. Xu, et al., Nano Energy 11(2015) 728-735. doi: 10.1016/j.nanoen.2014.11.042
9. [9]
  S. De, T.M. Higgins, P.E. Lyons, et al., ACS Nano 3(2009) 1767-1774. doi: 10.1021/nn900348c
10. [10]
  Z.Y. Fan, H. Razavi, J.W. Do, et al., Nat. Mater. 8(2009) 648-653. doi: 10.1038/nmat2493
11. [11]
  S.M. Paek, E. Yoo, I. Honma, Nano Lett. 9(2009) 72-75. doi: 10.1021/nl802484w
12. [12]
  G.M. Zhou, S.F. Pei, L. Li, et al., Adv. Mater. 26(2014) 625-631. doi: 10.1002/adma.201302877
13. [13]
  I. Chang, T. Park, J. Lee, et al., Int. J. Hydrogen Energy 41(2016) 6013-6019. doi: 10.1016/j.ijhydene.2016.02.087
14. [14]
  T. Park, Y.S. Kang, S. Jang, et al., NPG Asia Mater. 9(2017) e384. doi: 10.1038/am.2017.72
15. [15]
  F. Ning, X. He, Y. Shen, et al., ACS Nano 11(2017) 5982-5991. doi: 10.1021/acsnano.7b01880
16. [16]
  L.B. Dong, C.J. Xu, Y. Li, et al., J. Mater. Chem. A 4(2016) 4659-4685. doi: 10.1039/C5TA10582J
17. [17]
  Z. Weng, Y. Su, D.W. Wang, et al., Adv. Energy Mater. 1(2011) 917-922. doi: 10.1002/aenm.v1.5
18. [18]
  Q. Wu, Y.X. Xu, Z.Y. Yao, A.R. Liu, G.Q. Shi, ACS Nano 4(2010) 1963-1970. doi: 10.1021/nn1000035
19. [19]
  B.S. Shen, H. Wang, L.J. Wu, et al., Chin. Chem. Lett. 27(2016) 1586-1591. doi: 10.1016/j.cclet.2016.04.012
20. [20]
  G. Eda, G. Fanchini, M. Chhowalla, Nat. Nanotechnol. 3(2008) 270-274. doi: 10.1038/nnano.2008.83
21. [21]
  Q. Cao, H.S. Kim, N. Pimparkar, et al., Nature 454(2008) 495-U494. doi: 10.1038/nature07110
22. [22]
  D. Lee, J. Mazumder, Opt. Laser Technol. 99(2018) 315-325. doi: 10.1016/j.optlastec.2017.09.016
23. [23]
  S. Kosch, A. Rheinfeld, S.V. Erhard, A. Jossen, J. Power Sources 342(2017) 666-676. doi: 10.1016/j.jpowsour.2016.12.110
24. [24]
  S. H. Ng, F. La Mantia, P. Novak, Angew. Chem. Int. Ed. 48(2009) 528-532. doi: 10.1002/anie.v48:3
25. [25]
  W. Ren, F. Li, H.M. Cheng, J. Phys. Chem. B 110(2006) 16941-16946. doi: 10.1021/jp062526x
26. [26]
  P.X. Hou, W.S. Li, S.Y. Zhao, et al., ACS Nano 8(2014) 7156-7162. doi: 10.1021/nn502120k
27. [27]
  Q.F. Liu, W.C. Ren, Z.G. Chen, et al., ACS Nano 2(2008) 1722-1728. doi: 10.1021/nn8003394
28. [28]
  W.C. Ren, F. Li, H.M. Cheng, J. Phys. Chem. B 110(2006) 16941-16946. doi: 10.1021/jp062526x
29. [29]
  Q. Zhang, J.Q. Huang, M.Q. Zhao, W.Z. Qian, F. Wei, ChemSusChem 4(2011) 864-889. doi: 10.1002/cssc.201100177
30. [30]
  C.W. Zhang, L.B. Xu, J.F. Chen, Chin. Chem. Lett. 27(2016) 832-836. doi: 10.1016/j.cclet.2016.02.025
31. [31]
  L. Zou, J. Fan, Y. Zhou, et al., Nano Res. 8(2015) 2777-2788. doi: 10.1007/s12274-015-0784-0
32. [32]
  L. Zou, J. Guo, J. Liu, et al., J. Power Sources 248(2014) 356-362. doi: 10.1016/j.jpowsour.2013.09.086
33. [33]
  G.M. Zhou, D.W. Wang, F. Li, et al., Energy Environ. Sci. 5(2012) 8901-8906. doi: 10.1039/c2ee22294a
34. [34]
  L.B. Hu, H. Wu, F. La Mantia, Y.A. Yang, Y. Cui, ACS Nano 4(2010) 5843-5848. doi: 10.1021/nn1018158
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2. [2]
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3. [3]
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4. [4]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
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13. [13]
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17. [17]
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