Citation: Zhu Xiaohui, Jiang Wei, Cui Weirong, Liang Ruping, Zhang Li, Qiu Jianding. Facile surface modification of mesoporous silica with heterocyclic silanes for efficiently removing arsenic[J]. Chinese Chemical Letters, ;2019, 30(6): 1133-1136. doi: 10.1016/j.cclet.2019.02.022 shu

Facile surface modification of mesoporous silica with heterocyclic silanes for efficiently removing arsenic

Zhu Xiaohui ^a ,
Jiang Wei ^a ,
Cui Weirong ^a ,
Liang Ruping ^a ,
Zhang Li ^a ,
Qiu Jianding ^a,b,*,

a.
College of Chemistry, Nanchang University, Nanchang 330031, China
b.
Environmental Protection Materials and Equipment Engineering Technology Center of Jiangxi, Department of Materials and Chemical Engineering, Pingxiang University, Pingxiang 337055, China

jdqiu@ncu.edu.cn

Received Date: 29 December 2018
Revised Date: 13 February 2019
Accepted Date: 22 February 2019
Available Online: 22 June 2019

Figures(4)

Arsenic being one of the most toxic heavy metals has long been a focus of concern due to its gravest threats to human health and environment. Herein, we employ a new method named ring-opening click reaction to synthesize thiol-and amino-bifunctionalized SBA-15 (denoted as bi-SBA-15) for directly remove As(Ⅲ) without preoxidation As(Ⅲ) to As(Ⅴ) from contaminated water. Quite different from commonly modified with trialkoxysilanes, ring-opening click reaction is substantially faster (0.5-2 h at 25 ℃) and more efficient. The synthesized bi-SBA-15 exhibits excellent adsorption performance of As(Ⅲ) and As(Ⅴ) in an aqueous solution with a great adsorption capacity (33.70 mg/g and 42.66 mg/g, respectively), a very short equilibrium time (< 30 min), which is much faster than those of other adsorbents reported previously. The excellent adsorption performance of bi-SBA-15 can be maintained with a wide pH range (3-8), various anions and natural organic matter, which provides an effective approach and a new insight to clean arsenic-contaminated water.
- Arsenite,
- Arsenate,
- SBA-15,
- Remove,
- Click reaction,
- Synergistic effect
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