Citation: Sun Yimeng, Meng Yan, Jiang Jian, Sun Hui, Li Tiesheng. Glycyrrhizic acid based self-assembled helical nanostructures as scaffolds for asymmetric Diels-Alder reaction[J]. Chinese Chemical Letters, ;2019, 30(5): 966-968. doi: 10.1016/j.cclet.2019.02.015 shu

Glycyrrhizic acid based self-assembled helical nanostructures as scaffolds for asymmetric Diels-Alder reaction

Sun Yimeng ^a,b ,
Meng Yan ^b ,
Jiang Jian ^b,*, ,
Sun Hui ^b ,
Li Tiesheng ^a,*,

a.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China
b.
National Centre for Nanoscience and Technology, Beijing 100190, China

jiangj@nanoctr.cn

lts34@zzu.edu.cn

Received Date: 28 December 2018
Revised Date: 1 February 2019
Accepted Date: 20 February 2019
Available Online: 20 May 2019

Figures(3)

Glycyrrhizic acid (GA), as a traditional herbal, can self-assemble into helical nanofiber in the water. The formed helical nanostructures can be employed as scaffolds for asymmetric Diels-Alder reaction. Through co-assembling with a series of achiral copper-ligands, the chirality of GA helical nanostructures can be transferred to catalytic site, and resulted assemblies showed moderated enantioselectivity toward catalysis of Diels-Alder reaction.
- Glycyrrhizic acid,
- Helical nanofiber,
- Co-assembly,
- Asymmetric catalysis,
- Diels-Alder reaction
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