Citation: Zeng Mingyang, Zhang Li, Wu Dandan, Ma Jun, Zhang Cao, Li Shujuan. Asymmetric supercapacitors based on high capacitance Ni₆MnO₈ and graphene[J]. Chinese Chemical Letters, ;2019, 30(6): 1329-1334. doi: 10.1016/j.cclet.2019.01.026 shu

Asymmetric supercapacitors based on high capacitance Ni₆MnO₈ and graphene

Zeng Mingyang ^a,1 ,
Zhang Li ^a,*1, ,
Wu Dandan ^a ,
Ma Jun ^a ,
Zhang Cao ^a ,
Li Shujuan ^b,*,

a.
Department of Physics, School of Science, Lanzhou University of Technology, Lanzhou 730050, China
b.
Institute for Mathematics, Free University of Berlin, Berlin D-14195, Germany

zhangli@lut.cn

Shujuan.Li@fu-berlin.de

Received Date: 5 December 2018
Revised Date: 18 January 2019
Accepted Date: 23 January 2019
Available Online: 25 June 2019

Figures(5)

Supercapacitors with high energy density and high power density have attracted numerous attentions. Here, we successfully synthesized Ni₆MnO₈ material by a fast, facile, and cost-effective method, which the area specific capacitance was found to be as high as 1113 mF/cm² at a current density of 1 mA/cm². Further, the asymmetric supercapacitor was assembled by using Ni₆MnO₈ as the positive electrode and graphene as the negative electrode with an operation potential from 0 to 1.4 V. It exhibited an area specific capacitance of 69.1m F/cm² at 0.5 mA/cm² and stable cycling performance which presented about 80% capacitance retention after 5000 cycles at 5 mA/cm². The energy density of graphene//Ni₆MnO₈ supercapacitors was calculated to be 18.81 mWh/cm² at a power density of 350.1 mW/cm² and still remained 5.8 mWh/cm² at a power density of 6990.7 mW/cm², meaning that the asymmetric supercapacitor combine excellent power density and energy density.
- Ni₆MnO₈,
- Electrode,
- Asymmetric supercapacitors,
- Power density,
- Energy density
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Asymmetric supercapacitors based on high capacitance Ni₆MnO₈ and graphene