Citation: Zhang Zibin, Sun Kechang, Li Shijun, Yu Guocan. A pillar[5]arene-based molecular grapple of hexafluorophosphate[J]. Chinese Chemical Letters, ;2019, 30(5): 957-960. doi: 10.1016/j.cclet.2019.01.018 shu

A pillar[5]arene-based molecular grapple of hexafluorophosphate

Zhang Zibin ^a,*, ,
Sun Kechang ^a ,
Li Shijun ^a ,
Yu Guocan ^b,*,

a.
Hangzhou Normal University, Hangzhou 310036, China
b.
Laboratory of Molecular Imaging and Nanomedicine, National Institute of Biomedical Imaging and Bioengineering, National Institutes of Health, Bethesda 20892, United States

zzhang@hznu.edu.cn

guocan.yu@nih.gov

Received Date: 22 December 2018
Revised Date: 2 January 2019
Accepted Date: 15 January 2019
Available Online: 21 May 2019

Figures(5)

A symmetric pillararene-based receptor containing ten triazole units was synthesized. Interestingly, it formed 1:1 complexes instead of 1:2 with different halide anions. This was caused by the cooperative multivalent hydrogen-bond interactions between the triazole protons on one side of the receptor and the halide anion, which changed its structure from pillar to conical. However, by the regulation of the effector F^-, it can work like an excavator grapple selectively grasps a PF₆^- anion.
- Pillar[5]arene,
- Molecular machine,
- Anion receptors,
- Molecular recognition
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