Citation: Huang Guihua, Huang Yipeng, Xu Wei, Yao Qiuhong, Liu Xiaofang, Ding Caifeng, Chen Xi. Cesium lead halide perovskite nanocrystals for ultraviolet and blue light blocking[J]. Chinese Chemical Letters, ;2019, 30(5): 1021-1023. doi: 10.1016/j.cclet.2018.12.028 shu

Cesium lead halide perovskite nanocrystals for ultraviolet and blue light blocking

Huang Guihua ^a ,
Huang Yipeng ^b ,
Xu Wei ^b ,
Yao Qiuhong ^a ,
Liu Xiaofang ^c ,
Ding Caifeng ^d ,
Chen Xi ^b,*,

a.
Institute of Analytical Technology and Smart Instruments, College of Environment and Public Health, Xiamen Huaxia University, Xiamen 361024, China
b.
State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen 361005, China
c.
Department of Anesthesiology, Xiamen Maternal and Children Hospital, Xiamen 361003, China
d.
Key Laboratory of Sensor Analysis of Tumor Marker, Ministry of Education, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China

xichen@xmu.edu.cn

Received Date: 22 October 2018
Revised Date: 24 December 2018
Accepted Date: 25 December 2018
Available Online: 26 May 2018

Figures(4)

Using cesium lead halide perovskite nanocrystals, CsPb(Cl/Br)₃, as a light absorber, we report a highly effective UV and blue light blocking film. The CsPb(Cl/Br)₃ nanocrystals are well dispersed in the ethyl cellulose (EC) matrix to compose a UV and blue light shielding film, and the absorption edge of the film is tunable by adjusting Cl to Br ratio using anion exchange. The CsPbCl₂Br-EC film exhibits a transmittance of 5% at 459 nm, 90% at 478 nm and 95% in the range of 500-800 nm, which makes it excellent for UV and blue light shielding. In addition, the as-prepared EC-CsPb(Cl/Br)₃ film shows excellent photostability under UV irradiation. Results demonstrate that this EC-CsPb(Cl/Br)₃ based materials with sharp absorbance edges, tunable blocking wavelength, and high photostability can be useful for the applications in UV and blue light blocking and optical filters
- Perovskite nanocrystals,
- UV blocking,
- Blue light blocking,
- Cesium lead halide nanocrystals,
- Tunable adsorption edge
1. [1]
  J. Wu, S. Seregard, P.V. Algvere, Surv. Ophthalmol. 51(2006) 461-481. doi: 10.1016/j.survophthal.2006.06.009
2. [2]
  R. Sarkany, Medicine 45(2017) 444-447. doi: 10.1016/j.mpmed.2017.04.009
3. [3]
  A.R. Young, J. Claveau, A.B. Rossi, J. Am. Acad. Dermatol. 76(2017) S100-S109. doi: 10.1016/j.jaad.2016.09.038
4. [4]
  P.V. Algvere, J. Marshall, S. Seregard, Acta Ophthalmol. Scand. 84(2006) 4-15.
5. [5]
  Z. Yu, S. Qiu, X. Chen, et al., Neuroscience 270(2014) 158-167. doi: 10.1016/j.neuroscience.2014.04.013
6. [6]
  T. Ueda, T. Nakanishi-Ueda, H. Yasuhara, R. Koide, W.W. Dawson, Exp. Eye Res. 89(2009) 863-868. doi: 10.1016/j.exer.2009.07.018
7. [7]
  I. Jaadane, P. Boulenguez, S. Chahory, et al., Free Radical Bio. Med. 84(2015) 373-384. doi: 10.1016/j.freeradbiomed.2015.03.034
8. [8]
  C.B. Dipl-Biol, M. Schulz, T. Laube, J. Cataract Refr. Surg. 34(2008) 1161-1166. doi: 10.1016/j.jcrs.2008.03.039
9. [9]
  C. Han, F. Wang, C. Gao, et al., J. Mater. Chem. C Mater. Opt. Electron. Devices 3(2015) 5065-5072. doi: 10.1039/C4TC02880E
10. [10]
  L. Wallenhorst, L. Gurău, A. Gellerich, et al., Appl. Surf. Sci. 434(2018) 1183-1192. doi: 10.1016/j.apsusc.2017.10.214
11. [11]
  X. Wu, J. Wang, G. Zhang, et al., Appl. Catal. B-Environ. 201(2017) 128-136. doi: 10.1016/j.apcatb.2016.08.030
12. [12]
  J.Y. Huang, S.H. Li, M.Z. Ge, et al., J. Mater. Chem. A Mater. Energy Sustain. 3(2015) 2825-2832. doi: 10.1039/C4TA05332J
13. [13]
  X. Li, J. Wang, Z. Hu, M. Li, K. Ogino, Chin. Chem. Lett. 29(2018) 166-170. doi: 10.1016/j.cclet.2017.05.020
14. [14]
  H.Y. Wang, Y. Yang, X. Li, L.J. Li, C. Wang, Chin. Chem. Lett. 21(2010) 1119-1123. doi: 10.1016/j.cclet.2010.03.009
15. [15]
  S. Xie, J. Zhao, B. Zhang, et al., ACS Appl. Mater. Interfaces 7(2015) 17558-17564. doi: 10.1021/acsami.5b04231
16. [16]
  B. Xue, Z. Zhang, Y. Sun, et al., Carbohyd. Polym. 186(2018) 176-183. doi: 10.1016/j.carbpol.2017.12.088
17. [17]
  M.A. Green, A. Ho-Baillie, H.J. Snaith, Nat. Photonics 8(2014) 506-514. doi: 10.1038/nphoton.2014.134
18. [18]
  F. Zheng, D. Saldana-Greco, S. Liu, A.M. Rappe, J. Phys. Chem. Lett. 6(2015) 4862-4872. doi: 10.1021/acs.jpclett.5b01830
19. [19]
  G.L. Yang, H.Z. Zhong, Chin. Chem. Lett. 27(2016) 1124-1130. doi: 10.1016/j.cclet.2016.06.047
20. [20]
  L.C. Schmidt, A. Pertegas, S. Gonzalez-Carrero, et al., J. Am. Chem. Soc. 136(2014) 850-853. doi: 10.1021/ja4109209
21. [21]
  F. Zhang, H. Zhong, C. Chen, et al., ACS Nano 9(2015) 4533-4542. doi: 10.1021/acsnano.5b01154
22. [22]
  L. Protesescu, S. Yakunin, M.I. Bodnarchuk, et al., Nano Lett. 15(2015) 3692-3696. doi: 10.1021/nl5048779
23. [23]
  A. Swarnkar, R. Chulliyil, V.K. Ravi, et al., Angew. Chem. Int. Ed. 54(2015) 15424-15428. doi: 10.1002/anie.201508276
24. [24]
  Y. Wang, X. Li, J. Song, et al., Adv. Mater. 27(2015) 7101-7108. doi: 10.1002/adma.201503573
25. [25]
  J. Song, J. Li, X. Li, et al., Adv. Mater. 27(2015) 7162-7167. doi: 10.1002/adma.201502567
26. [26]
  Y. Wang, X. Li, X. Zhao, et al., Nano Lett. 16(2016) 448-453. doi: 10.1021/acs.nanolett.5b04110
27. [27]
  S. Yakunin, L. Protesescu, F. Krieg, et al., Nat. Commun. 6(2015) 8056. doi: 10.1038/ncomms9056
28. [28]
  Q.A. Akkerman, V. D'Innocenzo, S. Accornero, et al., J. Am. Chem. Soc. 137(2015) 10276-10281. doi: 10.1021/jacs.5b05602
29. [29]
  G. Nedelcu, L. Protesescu, S. Yakunin, et al., Nano Lett. 15(2015) 5635-5640. doi: 10.1021/acs.nanolett.5b02404
30. [30]
  F. Palazon, Q.A. Akkerman, M. Prato, L. Manna, ACS Nano 10(2016) 1224-1230. doi: 10.1021/acsnano.5b06536
31. [31]
  G. Grancini, V. D'Innocenzo, E.R. Dohner, et al., Chem. Sci. 6(2015) 7305-7310. doi: 10.1039/C5SC02542G
32. [32]
  J.F. Galisteo-Lopez, M. Anaya, M.E. Calvo, H. Miguez, J. Phys. Chem. Lett. 6(2015) 2200-2205. doi: 10.1021/acs.jpclett.5b00785
33. [33]
  A.M.A. Leguy, Y. Hu, M. Campoy-Quiles, et al., Chem. Mater. 27(2015) 3397-3407. doi: 10.1021/acs.chemmater.5b00660
34. [34]
  G.E. Eperon, S.N. Habisreutinger, T. Leijtens, et al., ACS Nano 9(2015) 9380-9393. doi: 10.1021/acsnano.5b03626
1. [1]
  Liwen Wang , Boyang Wang , Siyu Lu , Shubo Lv , Xiaoli Qu . High quantum yield yellow emission carbon dots for the construction of blue light blocking films. Chinese Chemical Letters, 2025, 36(2): 110497-. doi: 10.1016/j.cclet.2024.110497
2. [2]
  Xiaomeng Hu , Jie Yu , Lijie Sun , Linfeng Zhang , Wei Zhou , Dongpeng Yan , Xinrui Wang . Synthesis of an AVB@ZnTi-LDH composite with synergistically enhance UV blocking activity and high stability for potential application in sunscreen formulations. Chinese Chemical Letters, 2024, 35(11): 109466-. doi: 10.1016/j.cclet.2023.109466
3. [3]
  Le Han , Zhou Yuan , Bohan Li , Yuchi Zhang , Lin Yang , Yan Xu . Highly-stable cesium lead halide perovskite CsPbBr₃/CsPb₂Br₅ heteronanocrystals in zeolitic imidazolate framework-8 for antibiotic photodegradation. Chinese Chemical Letters, 2025, 36(6): 110349-. doi: 10.1016/j.cclet.2024.110349
4. [4]
  Husitu Lin , Shuangkun Zhang , Dianfa Zhao , Yongkang Wang , Wei Liu , Fan Yang , Jianjun Liu , Dongpeng Yan , Zhanpeng Wu . Flexible polyphosphazene nanocomposite films: Enhancing stability and luminescence of CsPbBr₃ perovskite nanocrystals. Chinese Chemical Letters, 2025, 36(4): 109795-. doi: 10.1016/j.cclet.2024.109795
5. [5]
  Zhaojun Liu , Zerui Mu , Chuanbo Gao . Alloy nanocrystals: Synthesis paradigms and implications. Chinese Journal of Structural Chemistry, 2023, 42(11): 100156-100156. doi: 10.1016/j.cjsc.2023.100156
6. [6]
  Hua Tong , Haibo Li , Wei Liu , Gangfeng Ouyang . Lead-free organic antimony halide with dual-band intrinsic white light emission for warm WLED directly. Chinese Journal of Structural Chemistry, 2025, 44(10): 100678-100678. doi: 10.1016/j.cjsc.2025.100678
7. [7]
  Huijiao Fu , Peiqin Liang , Qianwen Chen , Yan Wang , Guang Li , Xuzi Cai , Shengtao Wang , Kun Chen , Shengying Shi , Zhiqiang Yu , Xuefeng Wang . COX-2 blocking therapy in cisplatin chemosensitization of ovarian cancer: An allicin-based nanomedicine approach. Chinese Chemical Letters, 2024, 35(8): 109241-. doi: 10.1016/j.cclet.2023.109241
8. [8]
  Caixia Li , Yi Qiu , Yufeng Zhao , Wuliang Feng . Self assembled electron blocking and lithiophilic interface towards dendrite-free solid-state lithium battery. Chinese Chemical Letters, 2024, 35(4): 108846-. doi: 10.1016/j.cclet.2023.108846
9. [9]
  Yiming Yang , Lichao Sun , Qingfeng Zhang . Plasmonic nanocrystals with intrinsic chirality: Biomolecule-directed synthesis and applications. Chinese Journal of Structural Chemistry, 2025, 44(1): 100467-100467. doi: 10.1016/j.cjsc.2024.100467
10. [10]
  Yongqiang Ji , Donglin Jia , Fan Xu , Zhengwei Li , Lin Zhang , Le Li , Hengwei Qiu . Rise of colloidal silver bismuth sulfide nanocrystals solar cells. Chinese Chemical Letters, 2026, 37(2): 112054-. doi: 10.1016/j.cclet.2025.112054
11. [11]
  Lian Sun , Honglei Wang , Ming Ma , Tingting Cao , Leilei Zhang , Xingui Zhou . Shape and composition evolution of Pt and Pt₃M nanocrystals under HCl chemical etching. Chinese Chemical Letters, 2024, 35(9): 109188-. doi: 10.1016/j.cclet.2023.109188
12. [12]
  Linke Zhang , Tao Pang , Lingwei Zeng , Feng Huang , Daqin Chen . Recent progress of fluoride core-shell nanocrystals: Manipulating the non-steady-state of upconversion luminescence. Chinese Journal of Structural Chemistry, 2025, 44(11): 100713-100713. doi: 10.1016/j.cjsc.2025.100713
13. [13]
  Jing Cao , Dezheng Zhang , Bianqing Ren , Ping Song , Weilin Xu . Mn incorporated RuO₂ nanocrystals as an efficient and stable bifunctional electrocatalyst for oxygen evolution reaction and hydrogen evolution reaction in acid and alkaline. Chinese Chemical Letters, 2024, 35(10): 109863-. doi: 10.1016/j.cclet.2024.109863
14. [14]
  Tsegaye Tadesse Tsega , Jiantao Zai , Chin Wei Lai , Xin-Hao Li , Xuefeng Qian . Earth-abundant CuFeS2 nanocrystals@graphite felt electrode for high performance aqueous polysulfide/iodide redox flow batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100192-100192. doi: 10.1016/j.cjsc.2023.100192
15. [15]
  Yining Li , Shimei Wu , Lantao Chen , Haosen Fan , Yufei Zhang , Lingxing Zeng . Multiple yolks-shell cobalt phosphosulfide nanocrystals encapsulating into rich heteroatoms co-doped carbon frameworks for advanced sodium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(9): 110371-. doi: 10.1016/j.cclet.2024.110371
16. [16]
  Guojun Zhou , Qiqiong Ren , Yanting Wang , Nan Zhang , Yilin Mao , Pei Wang , Xian-Ming Zhang . Excitation-dependent tunable photoluminescence in CsCdCl3 all-inorganic perovskite for anti-counterfeiting. Chinese Journal of Structural Chemistry, 2026, 45(2): 100774-100774. doi: 10.1016/j.cjsc.2025.100774
17. [17]
  Tian Yang , Yi Liu , Lina Hua , Yaoyao Chen , Wuqian Guo , Haojie Xu , Xi Zeng , Changhao Gao , Wenjing Li , Junhua Luo , Zhihua Sun . Lead-free hybrid two-dimensional double perovskite with switchable dielectric phase transition. Chinese Chemical Letters, 2024, 35(6): 108707-. doi: 10.1016/j.cclet.2023.108707
18. [18]
  Dongying Fu , Lin Pan , Yanli Ma , Yue Zhang . Bilayered Dion–Jacobson lead-iodine hybrid perovskite with aromatic spacer for broadband photodetection. Chinese Chemical Letters, 2025, 36(2): 109621-. doi: 10.1016/j.cclet.2024.109621
19. [19]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641
20. [20]
  Xiuwen Xu , Quan Zhou , Yacong Wang , Yunjie He , Qiang Wang , Yuan Wang , Bing Chen . Expanding the toolbox of metal-free organic halide perovskite for X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109272-. doi: 10.1016/j.cclet.2023.109272

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1933)
HTML views(60)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142