Citation: Long Shuangshuang, Chi Weijie, Miao Lu, Qiao Qinglong, Liu Xiaogang, Xu Zhaochao. Strong π-π stacking interactions led to the mis-assignment of dimer emissions to the monomers of 1-acetylpyrene[J]. Chinese Chemical Letters, ;2019, 30(3): 601-604. doi: 10.1016/j.cclet.2018.12.008 shu

Strong π-π stacking interactions led to the mis-assignment of dimer emissions to the monomers of 1-acetylpyrene

Long Shuangshuang ^a,c ,
Chi Weijie ^b ,
Miao Lu ^a ,
Qiao Qinglong ^a,*, ,
Liu Xiaogang ^b,*, ,
Xu Zhaochao ^a,*,

a.
CAS Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
b.
Fluorescence Research Group, Singapore University of Technology and Design, Singapore 487372, Singapore
c.
University of Chinese Academy of Sciences, Beijing 100039, China

qqlqiao@dicp.ac.cn

xiaogang_liu@sutd.edu.sg

zcxu@dicp.ac.cn

Received Date: 3 December 2018
Revised Date: 4 December 2018
Accepted Date: 5 December 2018
Available Online: 5 March 2018

Figures(8)

Understanding relationships between molecular structures and fluorescent properties is critical to enable rational deployment of fluorophores. 1-Acetylpyrene is an important pyrene-derivative, used extensively as an environment-sensitive probe. In the past, the fluorescence of 1-acetylpyrene was considered to be polarity-sensitive with a large positive solvatochromism, and its monomer emissions were believed in the range of 410-470 nm. In this paper, our experimental and theoretical studies showed that the monomer fluorescence of 1-acetylpyrene is centered at ~390 nm, which is similar to that of pyrene dyes and not polarity-sensitive. Previously observed "monomer emission" has been re-assigned to that of dimers, which represent the dominant existence form of 1-acetylpyrene in the solution phase, as a result of strong intermolecular π-π stacking interactions.
- 1-Acetylpyrene,
- Pyrene,
- Aggregation,
- Monomer,
- Excimer
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