Citation: Men Yana, Su Jun, Wang Xiangli, Cai Ping, Cheng Gongzhen, Luo Wei. NiPt nanoparticles supported on CeO₂ nanospheres for efficient catalytic hydrogen generation from alkaline solution of hydrazine[J]. Chinese Chemical Letters, ;2019, 30(3): 634-637. doi: 10.1016/j.cclet.2018.11.010 shu

NiPt nanoparticles supported on CeO₂ nanospheres for efficient catalytic hydrogen generation from alkaline solution of hydrazine

Men Yana ^a,1 ,
Su Jun ^b,1 ,
Wang Xiangli ^c ,
Cai Ping ^a,*, ,
Cheng Gongzhen ^a ,
Luo Wei ^a,*,

a.
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China
b.
Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China
c.
No. 1 Middle School Affiliated to Central China Normal University, Wuhan 430075, China

caiping@whu.edu.cn

wluo@whu.edu.cn

Received Date: 19 September 2018
Revised Date: 1 November 2018
Accepted Date: 12 November 2018
Available Online: 12 March 2018

Figures(4)

Searching for highly efficient catalysts toward dehydrogenation of hydrazine for chemical hydrogen storage is highly desirable for the development of hydrogen economy. Herein, we report a simple in situ co-reduction synthesis of NiPt nanoparticles supported on CeO₂ nanospheres and their superior catalytic performance for hydrogen generation from alkaline solution of hydrazine at room temperature. Thanks to the strong electronic interaction arising from synergistic effect at atomic lever and support-metal interaction between NiPt and CeO₂. The obtained Ni₅Pt₅-CeO₂ catalyst exhibits 100% hydrogen selectivity and superior catalytic performance for hydrogen generation from alkaline solution of hydrazine at room temperature, with a TOF value of 416 h^-1.
- Hydrogen storage,
- Hydrazine,
- Hydrogen evolution,
- CeO₂ nanospheres,
- Support-metal interaction
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NiPt nanoparticles supported on CeO2 nanospheres for efficient catalytic hydrogen generation from alkaline solution of hydrazine

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NiPt nanoparticles supported on CeO₂ nanospheres for efficient catalytic hydrogen generation from alkaline solution of hydrazine