Citation: Hua Zhengshen, Zhang Xin, Feng Xiaojing, Wang Xiaoran, He Jun, Wang Xin, Peng Huifen. Improved electrochemical properties in the Li₃Fe₂(PO₄)₃ by titanium and vanadium doping[J]. Chinese Chemical Letters, ;2019, 30(3): 792-796. doi: 10.1016/j.cclet.2018.11.004 shu

Improved electrochemical properties in the Li₃Fe₂(PO₄)₃ by titanium and vanadium doping

Hua Zhengshen ^a ,
Zhang Xin ^a,b,c ,
Feng Xiaojing ^a ,
Wang Xiaoran ^a ,
He Jun ^a ,
Wang Xin ^a ,
Peng Huifen ^a,b,c,*,

a.
School of Material Science & Engineering, Hebei University of Technology, Tianjin 300130, China
b.
Research Institute for Energy Equipment Materials, Hebei University of Technology, Tianjin 300130, China
c.
Tianjin Key Laboratory of Laminating Fabrication & Interface Control Technology for Advanced Materials, Tianji 300130, China

peng@hebut.edu.cn

Received Date: 2 July 2018
Revised Date: 29 October 2018
Accepted Date: 6 November 2018
Available Online: 11 March 2018

Figures(4)

The nominal Li_3-xFe_2-xTi_x(PO₄)_2.55(VO₄)_0.45 (x=0~0.3) compounds were synthesized by a sol-gel process. Different from the single VO₄^3- doping, further introduction of Ti⁴⁺ ion was easy to result in precipitation of a little secondary phases, besides the main NASICON products. The simultaneous substitution of Ti⁴⁺ and VO₄^3- for Fe³⁺ and PO₄^3-, respectively, in the Li₃Fe₂(PO₄)₃ resulted in a net improvement in the rate capability and cycling performance, as compared with the single Ti⁴⁺ or VO₄^3--substituted compound. The sample with x=0.2 presented a high initial discharging capacity of 125.4 mAh/g at the rate of 0.5C, about 25% higher than the Ti⁴⁺-substituted Li_2.8Fe_1.8Ti_0.2(PO₄)₃, and 102.6 mAh/g after 60 cycles at 2C, about 12% higher than the single VO₄^3--substituted one. The high rate performance between 0.5C to 10C suggested that this sample had a good stability and reversibility. These results proved that the combination of the Ti⁴⁺ substitution for Fe³⁺ with the VO₄^3- substitution for PO₄^3- was a promising method of improving electrochemical performance of the studied Li₃Fe₂(PO₄)₃ cathode material.
- Li₃Fe₂(PO₄)₃,
- Lithium ion battery,
- Cathode,
- Doping,
- Electrochemical property
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Improved electrochemical properties in the Li3Fe2(PO4)3 by titanium and vanadium doping

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通讯作者: 陈斌, bchen63@163.com

Improved electrochemical properties in the Li₃Fe₂(PO₄)₃ by titanium and vanadium doping