Citation: He Menglan, Chen Lijun, Jiang Bo, Tan Hongwei, Wang Cuihong, Yang Haibo. Facile construction of Zn(Ⅱ)-porphyrin-cored [5]rotaxane and its controllable aggregation behaviours[J]. Chinese Chemical Letters, ;2019, 30(1): 131-134. doi: 10.1016/j.cclet.2018.10.035 shu

Facile construction of Zn(Ⅱ)-porphyrin-cored [5]rotaxane and its controllable aggregation behaviours

He Menglan ^a ,
Chen Lijun ^a ,
Jiang Bo ^a ,
Tan Hongwei ^b ,
Wang Cuihong ^a,, ,
Yang Haibo ^a,,

a.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China
b.
Department of Chemistry, Beijing Normal University, Beijing 100050, China

Corresponding author: Wang Cuihong, chwang@chem.ecnu.edu.cn Yang Haibo, hbyang@chem.ecnu.edu.cn
Received Date: 8 September 2018
Revised Date: 24 October 2018
Accepted Date: 29 October 2018
Available Online: 31 January 2018

Figures(4)

Rotaxanes have attracted more and more attentions because of their diverse applications as sensors, catalysts, and functional materials. The construction of highly ordered and discrete multirotaxanes with the well-defined structure remains a challenge. Herein, a symmetric [5]rotaxane with zinc porphyrin as core and the neutral platinum-acetylide as the linkage was synthesized with high yield. The [5]rotaxane was well characterized with NMR spectroscopy and MALDI-TOF mass spectrometry. Interestingly, it was found that the [5]rotaxane showed the controllable aggregation behaviours in different solution compositions. For example, in non-polar solution, the [5]rotaxane could self-assemble into the largescaled solid nanospheres while the nanofibers were formed in polar solvent. Further investigation revealed that the [5]rotaxane displayed J-type aggregation in solution driven by π-π interaction. Notably, the similar structure without DPP[5]A formed the irregular morphology at the same condition, suggesting that the existence of rotaxanes endowed the complex with a relative rigid structure to facilitate the formation of the ordered aggregates.
- [5]rotaxane,
- Neutral platinum,
- Ordered nanostructures,
- Morphology aggregation
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