Citation: Sun Guanghui, Jin Yuekang, Wang Zhengming, Xu Hong, Chai Peng, Huang Weixin. Site-and surface species-dependent propylene oxidation with molecular oxygen on gold surface[J]. Chinese Chemical Letters, ;2018, 29(12): 1883-1887. doi: 10.1016/j.cclet.2018.10.027 shu

Site-and surface species-dependent propylene oxidation with molecular oxygen on gold surface

Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China

huangwx@ustc.edu.cn

Received Date: 30 September 2018
Revised Date: 19 October 2018
Accepted Date: 24 October 2018
Available Online: 30 December 2018

Figures(5)

Fundamental understandings of Au-catalyzed oxidation reactions with molecular oxygen are of great importance. Herein we report a successful preparation of molecularly-adsorbed O₂ species on a stepped Au(997) single crystal model surface via a near-ambient pressure and low-temperature oxygen exposure and their oxidation reactivity with propylene via temperature programmed desorption spectra and polarization-modulated reflection-absorption infrared spectra. O₂ molecularly adsorbs at the (111) step sites of Au(997) surface while C₃H₆ adsorbs at both (111) step sites and (111) terrace sites. C₃H₆(a) adsorbed at the (111) step sites is more stable than at the (111) terrace sites and its oxidation reactions are dominant; meanwhile, O₂(a) is much more reactive than O(a) and prefers combustion reaction of C₃H₆(a). C₃H₆(a) adsorbed at the (111) step sites undergoes combustion reactions with O₂(a) to produce CO₂ and CO at low temperatures and partial oxidation reactions with O(a) to produce acrolein at high temperatures while C₃H₆(a) adsorbed at the (111) terrace sites undergoes combustion and partial oxidation reactions with O₂(a) to respectively produce CO₂/CO and acrolein at low temperatures. These results reveal site-and surface species-dependent reaction behaviors of propylene oxidation with molecular O₂ on Au surfaces and provide a complete fundamental understanding of oxidation reactions with molecular O₂ on Au surface.
- Au(997) single crystal,
- Combustion,
- Partial oxidation,
- Acrolein,
- Reaction mechanism
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