Citation: Feng Sheng, Yan Pengcheng, Xu Li, Xia Jiexiang, Li Huaming. Exploitation of a photoelectrochemical sensing platform for bisphenol A quantitative determination using Cu/graphitic carbon nitride nanocomposites[J]. Chinese Chemical Letters, ;2018, 29(11): 1629-1632. doi: 10.1016/j.cclet.2018.08.010 shu

Exploitation of a photoelectrochemical sensing platform for bisphenol A quantitative determination using Cu/graphitic carbon nitride nanocomposites

Feng Sheng ^a,, ,
Yan Pengcheng ^b ,
Xu Li ^b ,
Xia Jiexiang ^b ,
Li Huaming ^b,,

a.
School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
b.
Institute for Energy Research, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China

Corresponding author: Feng Sheng, shfeng@cczu.edu.cn Li Huaming, lhm@ujs.edu.cn
Received Date: 23 June 2018
Revised Date: 21 August 2018
Accepted Date: 23 August 2018
Available Online: 24 November 2018

Figures(4)

A simple and effective photoelectrochemical sensor was fabricated by Cu/graphitic carbon nitride (Cu/gCN) composites for detecting bisphenol A. The Cu/g-CN composites were obtained via a solvothermal process in the presence of the copper-based ionic liquid. In view of localized surface plasmon resonance of Cu nanoparticles, Cu nanoparticles can promote light absorbance and rapid electron transport of g-CN. As a result, the Cu/g-CN composites obtained greatly enhancement of photocurrent, when compared to the pure g-CN. In addition, the introduction of bisphenol A can hinder electron-hole recombination, resulting in sensitive photoelectrochemical monitoring of bisphenol A. The detection limit of the bisphenol A photoelectrochemical sensor was below 0.012 μmol/L. The bisphenol A photoelectrochemical sensor exhibited an excellent stability and acceptable anti-interference. The photoelectrochemical sensor provided the promising platform to monitor bisphenol A at low concentration in water environment.
- Photoelectrochemical detection,
- Graphitic carbon nitride,
- Cu nanoparticles,
- Bisphenol A,
- Localized surface plasmon resonance
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