Citation: Wang Shengping, Hou Shihui, Wu Chao, Zhao Yujun, Ma Xinbin. RuCl₃ anchored onto post-synthetic modification MIL-101(Cr)-NH₂ as heterogeneous catalyst for hydrogenation of CO₂ to formic acid[J]. Chinese Chemical Letters, ;2019, 30(2): 398-402. doi: 10.1016/j.cclet.2018.06.021 shu

RuCl₃ anchored onto post-synthetic modification MIL-101(Cr)-NH₂ as heterogeneous catalyst for hydrogenation of CO₂ to formic acid

Wang Shengping ^a,b ,
Hou Shihui ^a,b ,
Wu Chao ^a,b ,
Zhao Yujun ^a,b,*, ,
Ma Xinbin ^a,b

a.
Key Laboratory for Green Chemical Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
b.
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China

yujunzhao@tju.edu.cn

Received Date: 25 April 2018
Revised Date: 7 June 2018
Accepted Date: 15 June 2018
Available Online: 18 February 2018

Figures(8)

A series of efficient ruthenium chloride (RuCl₃)-anchored MOF catalysts, such as RuCl₃@MIL-101(Cr)-Sal, and RuCl₃@MIL-101(Cr)-DPPB, have been successfully synthesized by post-synthetic modification (PSM) of the terminal amino of MIL-101(Cr)-NH₂ with salicylaldehyde, 2-diphenylphosphinobenzaldehyde (DPPBde) and anchoring of Ru(Ⅲ) ions. The stronger coordination electron donor interaction between Ru(Ⅲ) ions and chelating groups in the RuCl₃@MIL-101(Cr)-DPPB enhances its catalytic performance for CO₂ hydrogenation to formic acid. The turnover number (TON) of formic acid was up to 831 in reaction time of 2 h with dimethyl sulfoxide (DMSO) and water (H₂O) as mixed solvent, trimethylamine (Et₃N) as organic base, and PPh₃ as electronic additive.
- RuCl₃,
- MIL-101(Cr)-DPPB,
- Post-synthetic modification,
- Anchoring Ru(Ⅲ),
- Electron-donor substituent
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RuCl3 anchored onto post-synthetic modification MIL-101(Cr)-NH2 as heterogeneous catalyst for hydrogenation of CO2 to formic acid

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RuCl₃ anchored onto post-synthetic modification MIL-101(Cr)-NH₂ as heterogeneous catalyst for hydrogenation of CO₂ to formic acid