Citation: Yin Xianpeng, Dong Hao, Wang Shiqiang, Liang Yun, Gao Ning, Zhang Wanlin, Tian Li, Sun Fuwei, Li Guangtao. A multiple coupling approach to produce high-performance SERS substrates[J]. Chinese Chemical Letters, ;2019, 30(1): 179-182. doi: 10.1016/j.cclet.2018.06.013 shu

A multiple coupling approach to produce high-performance SERS substrates

Department of Chemistry, Key Lab of Organic Optoelectronics and Molecular Engineering, Tsinghua University, Beijing 100084, China

Corresponding author: Li Guangtao, LGT@mail.tsinghua.edu.cn
Received Date: 9 May 2018
Revised Date: 1 June 2018
Accepted Date: 7 June 2018
Available Online: 9 January 2018

Figures(4)

Creating hotspots with significantly enhanced electromagnetic (EF) field, efficiently placing target molecules in hotspot region, and achieving uniform and reproducible Raman signals are three critical issues for developing high-performance SERS substrates. In this work, large area gold nanoparticle cluster pillar array with a gold mirror at bottom was facilely fabricated by combined use of nanosphere lithography and self-assembly approach. It is both theoretically and experimentally found that through multiple coupling interactions, the electromagnetic fields at interparticle gaps within the gold clusters were significantly enhanced in our three-dimentional (3D) pillar array substrates, which can result in one order of magnitude stronger as compared with random gold clusters on a two-dimentional planar case. Due to the periodic stucture, our substrates also possess the capbility of producing highly uniform and reproducible SERS signals. Attractively, in our case, a photoresponsive polymer was used for the formation of pillar array structure. Its unique photoinduced deformation makes it possible to reversibly open and close the gaps of the closely packed Au NP array, thus enabling efficient placement or entrapment of probe molecules into hotspot sites between adjacent nanoparticles.
- Hotspots,
- Electromagnetic,
- Nanoparticles,
- Cluster array,
- SERS
1. [1]
  S.Y. Ding, E.M. You, Z.Q. Tian, M. Moskovits, Chem. Soc. Rev. 46(2017) 4042-4076. doi: 10.1039/C7CS00238F
2. [2]
  C. Hamon, L.M. Liz-Marzán, J. Colloid Interface Sci. 512(2018) 834-843. doi: 10.1016/j.jcis.2017.10.117
3. [3]
  Y.Z. Chu, M.G. Banaee, K.B. Crozier, ACS Nano 4(2010) 2804-2810. doi: 10.1021/nn901826q
4. [4]
  K.L. Kelly, E. Coronado, L.L. Zhao, G.C. Schatz, J. Phys. Chem. B 107(2003) 668-677.
5. [5]
  E. Ringe, J.M. McMahon, K. Sohn, et al., J. Phys. Chem. C 114(2010) 12511-12516. doi: 10.1021/jp104366r
6. [6]
  S.M. Nie, S.R. Emery, Science 275(1997) 1102-1106. doi: 10.1126/science.275.5303.1102
7. [7]
  S. Schlücker, Angew. Chem. Int. Ed. 53(2014) 4756-4795. doi: 10.1002/anie.201205748
8. [8]
  B. Yan, S.V. Boriskina, B.M. Reinhard, J. Phys. Chem. C 115(2011) 4578-4583. doi: 10.1021/jp112146d
9. [9]
  J.M. Nam, J.W. Oh, H. Lee, Y.D. Suh, Acc. Chem. Res. 49(2016) 2746-2755. doi: 10.1021/acs.accounts.6b00409
10. [10]
  C. Wang, L. Tian, W. Zhu, et al., Chem. Sci. 9(2018) 889-895. doi: 10.1039/C7SC03536E
11. [11]
  X.L. Zhang, X.H. Xiao, Z.G. Dai, et al., Nanoscale 9(2017) 3114-3120. doi: 10.1039/C6NR09592E
12. [12]
  H.Y. Chen, M.H. Lin, C.Y. Wang, Y.M. Chang, S. Gwo, J. Am. Chem. Soc.137(2015) 13698-13705. doi: 10.1021/jacs.5b09111
13. [13]
  E.C. Le Ru, P.G. Etchegoin, M. Meyer, J. Chem. Phys. 125(2006) 204701. doi: 10.1063/1.2390694
14. [14]
  D.D. Lin, Z.L. Wu, S.J. Li, et al., ACS Nano 11(2017) 1478-1487. doi: 10.1021/acsnano.6b06778
15. [15]
  B. Yan, A. Thubagere, W.R. Premasiri, et al., ACS Nano 3(2009) 1190-1202. doi: 10.1021/nn800836f
16. [16]
  L.L. Yang, B. Yan, W.R. Premasiri, et al., Adv. Funct. Mater. 20(2010) 2619-2628. doi: 10.1002/adfm.201000630
17. [17]
  J. Wang, L.L. Yang, S. Boriskina, B. Yan, B.M. Reinhard, Anal. Chem. 83(2011) 2243-2249. doi: 10.1021/ac103123r
18. [18]
  F.L. Yap, P. Thoniyot, S. Krishnan, S. Krishnamoorthy, ACS Nano 6(2012) 2056-2070. doi: 10.1021/nn203661n
19. [19]
  C. Leordean, M. Potara, S. Boca-Farcau, et al., J. Raman Spectrosc. 45(2014) 627-635. doi: 10.1002/jrs.v45.8
20. [20]
  W.D. Liu, B. Yang, Chin. Chem. Lett. 28(2017) 675-690. doi: 10.1016/j.cclet.2016.09.004
21. [21]
  K.N. Kanipe, P.P. Chidester, G.D. Stucky, M. Moskovits, ACS Nano 10(2016) 7566-7571. doi: 10.1021/acsnano.6b02564
22. [22]
  W.D. Li, F. Ding, J. Hu, S.Y. Chou, Opt. Express 19(2011) 3925-3936. doi: 10.1364/OE.19.003925
23. [23]
  T. Lee, J.S. Wi, A. Oh, et al., Nanoscale 10(2018) 3680-3687. doi: 10.1039/C7NR08066B
24. [24]
  M. Chirumamilla, A. Chirumamilla, A.S. Roberts, et al., Adv. Opt. Mater. 5(2017) 1600836. doi: 10.1002/adom.v5.4
25. [25]
  C.L. Haynes, R.P. Van Duyne, J. Phys. Chem. B 105(2001) 5599-5611. doi: 10.1021/jp010657m
26. [26]
  P.N. Njoki, I.I.S. Lim, D. Mott, et al., J. Phys. Chem. C 111(2007) 14664-14669. doi: 10.1021/jp074902z
27. [27]
  P. Rochon, E. Batalla, A. Natansohn, Appl. Phys. Lett. 66(1995) 136-138. doi: 10.1063/1.113541
1. [1]
  Feihu Wu , Gengwen Chen , Kaitao Lai , Shiqing Zhang , Yingchao Liu , Ruijian Luo , Xiaocong Wang , Pinzhi Cao , Yi Ye , Jiarong Lian , Junle Qu , Zhigang Yang , Xiaojun Peng . Non-specific/specific SERS spectra concatenation for precise bacteria classifications with few samples using a residual neural network. Chinese Chemical Letters, 2025, 36(1): 109884-. doi: 10.1016/j.cclet.2024.109884
2. [2]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
3. [3]
  Yuwen Zhu , Xiang Deng , Yan Wu , Baode Shen , Lingyu Hang , Yuye Xue , Hailong Yuan . Formation mechanism of herpetrione self-assembled nanoparticles based on pH-driven method. Chinese Chemical Letters, 2025, 36(1): 109733-. doi: 10.1016/j.cclet.2024.109733
4. [4]
  Shenglan Zhou , Haijian Li , Hongyi Gao , Ang Li , Tian Li , Shanshan Cheng , Jingjing Wang , Jitti Kasemchainan , Jianhua Yi , Fengqi Zhao , Wengang Qu . Recent advances in metal-loaded MOFs photocatalysts: From single atom, cluster to nanoparticle. Chinese Chemical Letters, 2025, 36(1): 110142-. doi: 10.1016/j.cclet.2024.110142
5. [5]
  Bohan Chen , Liming Gong , Jing Feng , Mingji Jin , Liqing Chen , Zhonggao Gao , Wei Huang . Research advances of nanoparticles for CAR-T therapy in solid tumors. Chinese Chemical Letters, 2024, 35(9): 109432-. doi: 10.1016/j.cclet.2023.109432
6. [6]
  Wei Su , Xiaoyan Luo , Peiyuan Li , Ying Zhang , Chenxiang Lin , Kang Wang , Jianzhuang Jiang . Phthalocyanine self-assembled nanoparticles for type Ⅰ photodynamic antibacterial therapy. Chinese Chemical Letters, 2024, 35(12): 109522-. doi: 10.1016/j.cclet.2024.109522
7. [7]
  Yiran Tao , Chunlei Dai , Zhaoxiang Xie , Xinru You , Kaiwen Li , Jun Wu , Hai Huang . Redox responsive polymeric nanoparticles enhance the efficacy of cyclin dependent kinase 7 inhibitor for enhanced treatment of prostate cancer. Chinese Chemical Letters, 2024, 35(8): 109170-. doi: 10.1016/j.cclet.2023.109170
8. [8]
  Yihao Zhang , Yang Jiao , Xianchao Jia , Qiaojia Guo , Chunying Duan . Highly effective self-assembled porphyrin MOCs nanomaterials for enhanced photodynamic therapy in tumor. Chinese Chemical Letters, 2024, 35(5): 108748-. doi: 10.1016/j.cclet.2023.108748
9. [9]
  Yixin Zhang , Ting Wang , Jixiang Zhang , Pengyu Lu , Neng Shi , Liqiang Zhang , Weiran Zhu , Nongyue He . Formation mechanism for stable system of nanoparticle/protein corona and phospholipid membrane. Chinese Chemical Letters, 2024, 35(4): 108619-. doi: 10.1016/j.cclet.2023.108619
10. [10]
  Keyang Li , Yanan Wang , Yatao Xu , Guohua Shi , Sixian Wei , Xue Zhang , Baomei Zhang , Qiang Jia , Huanhua Xu , Liangmin Yu , Jun Wu , Zhiyu He . Flash nanocomplexation (FNC): A new microvolume mixing method for nanomedicine formulation. Chinese Chemical Letters, 2024, 35(10): 109511-. doi: 10.1016/j.cclet.2024.109511
11. [11]
  Yujie Li , Ya-Nan Wang , Yin-Gen Luo , Hongcai Yang , Jinrui Ren , Xiao Li . Advances in synthetic biology-based drug delivery systems for disease treatment. Chinese Chemical Letters, 2024, 35(11): 109576-. doi: 10.1016/j.cclet.2024.109576
12. [12]
  Fereshte Hassanzadeh-Afruzi , Mina Azizi , Iman Zare , Ehsan Nazarzadeh Zare , Anwarul Hasan , Siavash Iravani , Pooyan Makvandi , Yi Xu . Advanced metal-organic frameworks-polymer platforms for accelerated dermal wound healing. Chinese Chemical Letters, 2024, 35(11): 109564-. doi: 10.1016/j.cclet.2024.109564
13. [13]
  Kang Wang , Qinglin Zhou , Weijin Li . Conductive metal-organic frameworks for electromagnetic wave absorption. Chinese Journal of Structural Chemistry, 2024, 43(10): 100325-100325. doi: 10.1016/j.cjsc.2024.100325
14. [14]
  Xuexia Lin , Yihui Zhou , Jiafu Hong , Xiaofeng Wei , Bin Liu , Chong-Chen Wang . Facile preparation of ZIF-8/ZIF-67-derived biomass carbon composites for highly efficient electromagnetic wave absorption. Chinese Chemical Letters, 2024, 35(9): 109835-. doi: 10.1016/j.cclet.2024.109835
15. [15]
  Ting Pan , Dinghu Zhang , Guomei You , Xiaoxia Wu , Chenguang Zhang , Xinyu Miao , Wenzhi Ren , Yiwei He , Lulu He , Yuanchuan Gong , Jie Lin , Aiguo Wu , Guoliang Shao . PD-L1 targeted iron oxide SERS bioprobe for accurately detecting circulating tumor cells and delineating tumor boundary. Chinese Chemical Letters, 2025, 36(1): 109857-. doi: 10.1016/j.cclet.2024.109857
16. [16]
  Bharathi Natarajan , Palanisamy Kannan , Longhua Guo . Metallic nanoparticles for visual sensing: Design, mechanism, and application. Chinese Journal of Structural Chemistry, 2024, 43(9): 100349-100349. doi: 10.1016/j.cjsc.2024.100349
17. [17]
  Ying Hou , Zhen Liu , Xiaoyan Liu , Zhiwei Sun , Zenan Wang , Hong Liu , Weijia Zhou . Laser constructed vacancy-rich TiO_2-x/Ti microfiber via enhanced interfacial charge transfer for operando extraction-SERS sensing. Chinese Chemical Letters, 2024, 35(9): 109634-. doi: 10.1016/j.cclet.2024.109634
18. [18]
  Zhi Li , Wenpei Li , Shaoping Jiang , Chuan Hu , Yuanyu Huang , Maxim Shevtsov , Huile Gao , Shaobo Ruan . Legumain-triggered aggregable gold nanoparticles for enhanced intratumoral retention. Chinese Chemical Letters, 2024, 35(7): 109150-. doi: 10.1016/j.cclet.2023.109150
19. [19]
  Feng Cui , Fangman Chen , Xiaochun Xie , Chenyang Guo , Kai Xiao , Ziping Wu , Yinglu Chen , Junna Lu , Feixia Ruan , Chuanxu Cheng , Chao Yang , Dan Shao . Scalable production of mesoporous titanium nanoparticles through sequential flash nanocomplexation. Chinese Chemical Letters, 2024, 35(4): 108681-. doi: 10.1016/j.cclet.2023.108681
20. [20]
  Ting Xie , Xun He , Lang He , Kai Dong , Yongchao Yao , Zhengwei Cai , Xuwei Liu , Xiaoya Fan , Tengyue Li , Dongdong Zheng , Shengjun Sun , Luming Li , Wei Chu , Asmaa Farouk , Mohamed S. Hamdy , Chenggang Xu , Qingquan Kong , Xuping Sun . CoSe₂ nanowire array enabled highly efficient electrocatalytic reduction of nitrate for ammonia synthesis. Chinese Chemical Letters, 2024, 35(11): 110005-. doi: 10.1016/j.cclet.2024.110005

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(699)
HTML views(41)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142