Citation: Zhang Zhitao, Zhao Na, Ma Kui, Cheng Qingpeng, Zhang Jing, Zheng Lirong, Tian Ye, Li Xingang. Isolated zinc in mordenite stabilizing carbonylation of dimethyl ether to methyl acetate[J]. Chinese Chemical Letters, ;2019, 30(2): 513-516. doi: 10.1016/j.cclet.2018.05.032 shu

Isolated zinc in mordenite stabilizing carbonylation of dimethyl ether to methyl acetate

Zhang Zhitao ^a ,
Zhao Na ^a ,
Ma Kui ^a ,
Cheng Qingpeng ^a ,
Zhang Jing ^b ,
Zheng Lirong ^b ,
Tian Ye ^a,*, ,
Li Xingang ^a,*,

a.
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin Key Laboratory of Applied Catalysis Science and Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
b.
Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China

tianye@tju.edu.cn

xingang_li@tju.edu.cn

Received Date: 6 March 2018
Revised Date: 11 May 2018
Accepted Date: 17 May 2018
Available Online: 18 February 2018

Figures(4)

Herein, we prepared a series of H-Zn-mordenite (H-Zn-MOR) catalysts by adding zinc source into the initial sols during the synthesis of mordenite (MOR). The results indicated that isolated Zn ions were highly dispersed in the catalysts. The addition of zinc led to the increase of Si/Al in the framework of MOR, the change of the distribution of acid sites and the change of acid strength. We investigated the catalytic performance of the H-Zn-MOR catalysts and the HMOR catalysts for carbonylation of dimethyl ether to methyl acetate. The addition of zinc improved the catalytic performance and made the drop of the conversion over the Zn-0.003 and Zn-0.005 catalysts to be about the half of that over the HMOR catalyst. We attributed it to the change of the acid properties, which further change the rate of coke deposition.
- Zinc,
- Mordenite,
- Dimethyl ether,
- Carbonylation,
- Acidic property
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