Citation: Sui Xianwei, Xie Xu-Ming. Creating super-tough and strong PA6/ABS blends using multi-phase compatibilizers[J]. Chinese Chemical Letters, ;2019, 30(1): 149-152. doi: 10.1016/j.cclet.2018.04.035 shu

Creating super-tough and strong PA6/ABS blends using multi-phase compatibilizers

Sui Xianwei ,
Xie Xu-Ming ^,

Key Laboratory of Advanced Materials(MOE), Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Corresponding author: Xie Xu-Ming, xxm-dce@mail.tsinghua.edu.cn
Received Date: 22 March 2018
Revised Date: 21 April 2018
Accepted Date: 27 April 2018
Available Online: 27 January 2018

Figures(4)

Polyamide/acrylonitrile-butadiene-styrene copolymer (PA/ABS) blends have drawn considerable attention from both academia and industry for their important applications in automotive and electronic areas. Due to poor miscibility of PA and ABS, developing an effective compatibilization strategy has been an urgent challenge to achieve prominent mechanical properties. In this study, we create a set of mechanically enhanced PA6/ABS blends using two multi-monomer melt-grafted compatibilizers, SEBSg-(MAH-co-St) and ABS-g-(MAH-co-St). The dispersed domain size is significantly decreased and meanwhile the unique "soft shell-encapsulating-hard core" structures form in the presence of compatibilizers. The optimum mechanical performances manifest an increase of 36% in tensile strength and an increase of 1300% in impact strength, compared with the neat PA6/ABS binary blend.
- Melt blending,
- Multi-phase compatibilizer,
- Morphology,
- Tensile properties,
- Super-tough
1. [1]
  R.A. Kudva, H. Keskkula, D.R. Paul, Polymer 39(1998) 2447-2460. doi: 10.1016/S0032-3861(97)00583-1
2. [2]
  D.R. Paul, C.B. Bucknall, Polymer Blends:Formulation and Performance, Wiley, New York, 2000.
3. [3]
  L.A. Utracki, Polymer Alloys and Blends:Thermodynamics and Rheology, Hanser, Munich, 1989.
4. [4]
  Y. Xu, C.M. Thurber, C.W. Macosko, T.P. Lodge, M.A. Hillmyer, Ind. Eng. Chem. Res. 53(2014) 4718-4725. doi: 10.1021/ie4043196
5. [5]
  M. Maric, C.W. Macosko, J. Polym. Sci. Part B Polym. Phys. 40(2002) 346-357. doi: 10.1002/(ISSN)1099-0488
6. [6]
  A. Adedeji, S. Lyu, C.W. Macosko, Macromolecules 34(2001) 8663-8668. doi: 10.1021/ma001944b
7. [7]
  C.W. Macosko, P. Guegan, A.K. Khandpur, et al., Macromolecules 29(1996) 5590-5598. doi: 10.1021/ma9602482
8. [8]
  X.M. Xie, Y. Chen, Z.M. Zhang, et al., Macromolecules 32(1999) 4424-4429. doi: 10.1021/ma9805046
9. [9]
  J. Kim, R.W. Sandoval, C.M. Dettmer, S.T. Nguyen, J.M. Torkelson, Polymer 49(2008) 2686-2697. doi: 10.1016/j.polymer.2008.04.008
10. [10]
  R. Bahrami, T.I. Lobling, H. Schmalz, A.H.E. Muller, V. Altstadt, Polymer 80(2015) 52-63. doi: 10.1016/j.polymer.2015.10.039
11. [11]
  R. Bahrami, T.I. Lobling, H. Schmalz, A.H.E. Muller, V. Altstadt, Polymer 109(2017) 229-237. doi: 10.1016/j.polymer.2016.12.044
12. [12]
  A. Bharati, R. Cardinaels, T. Van der Donck, et al., Polymer 108(2017) 483-492. doi: 10.1016/j.polymer.2016.12.015
13. [13]
  H. Koriyama, H.T. Oyama, T. Ougizawa, et al., Polymer 40(1999) 6381-6393. doi: 10.1016/S0032-3861(98)00856-8
14. [14]
  J.B. Zhang, T.P. Lodge, C.W. Macosko, Macromolecules 38(2005) 6586-6591. doi: 10.1021/ma050530l
15. [15]
  M. Harada, K. Iida, K. Okamoto, H. Hayashi, K. Hirano, Polym. Eng. Sci. 48(2008) 1359-1368. doi: 10.1002/(ISSN)1548-2634
16. [16]
  G.C. Liu, Y.S. He, J.B. Zeng, Q.T. Li, Y.Z. Wang, Biomacromolecules 15(2014) 4260-4271. doi: 10.1021/bm5012739
17. [17]
  C.M. Thurber, Y.W. Xu, J.C. Myers, T.P. Lodge, C.W. Macosko, ACS Macro Lett. 4(2015) 30-33. doi: 10.1021/mz500770y
18. [18]
  H.T. Wang, W.Y. Dong, Y.J. Li, ACS Macro Lett. 4(2015) 1398-1403. doi: 10.1021/acsmacrolett.5b00763
19. [19]
  A.M. Zolali, B.D. Favis, Polymer 114(2017) 277-288. doi: 10.1016/j.polymer.2017.02.093
20. [20]
  A.D. Todd, R.J. McEneany, V.A. Topolkaraev, C.W. Macosko, M.A. Hillmyer, Macromolecules 49(2016) 8988-8994. doi: 10.1021/acs.macromol.6b02080
21. [21]
  R. Greco, A. Sorrentino, Adv. Polym. Technol. 13(1994) 249-258. doi: 10.1002/adv.1994.060130401
22. [22]
  D.R. Paul, J.W. Barlow, J. Macromol. Sci. Rev. Macromol. Chem. Phys. C 18(1980) 109-168. doi: 10.1080/00222358008080917
23. [23]
  G.S. Wildes, T. Harada, H. Keskkula, et al., Polymer 40(1999) 3069-3082. doi: 10.1016/S0032-3861(98)00521-7
24. [24]
  M.P. Lee, A. Hiltner, E. Baer, Polymer 33(1992) 685-697. doi: 10.1016/0032-3861(92)90323-O
25. [25]
  Y.J. Li, H. Shimizu, Macromol. Rapid Commun. 26(2005) 710-715. doi: 10.1002/(ISSN)1521-3927
26. [26]
  R.A. Kudva, H. Keskkula, D.R. Paul, Polymer 41(2000) 239-258. doi: 10.1016/S0032-3861(99)00106-8
27. [27]
  R.A. Kudva, H. Keskkula, D.R. Paul, Polymer 41(2000) 225-237. doi: 10.1016/S0032-3861(99)00105-6
28. [28]
  X.Q. Liu, W. Yang, B.H. Xie, M.B. Yang, Mater. Des. 34(2012) 355-362. doi: 10.1016/j.matdes.2011.08.028
29. [29]
  B.K. Kim, Y.M. Lee, H.M. Jeong, Polymer 34(1993) 2075-2080. doi: 10.1016/0032-3861(93)90734-R
30. [30]
  B. Majumdar, H. Keskkula, D.R. Paul, Polymer 35(1994) 5453-5467. doi: 10.1016/S0032-3861(05)80009-6
31. [31]
  Y. Fu, H. Song, C. Zhou, H. Zhang, S. Sun, Polym. Bull. 70(2013) 1853-1862. doi: 10.1007/s00289-012-0879-7
32. [32]
  S. Shulin, C. Zhuo, S. Lili, Z. Huixuan, J. Appl. Polym. Sci. 121(2011) 909-915. doi: 10.1002/app.33648
33. [33]
  S. Sun, Z. Chen, H. Zhang, Polym. Bull. 61(2008) 443-452. doi: 10.1007/s00289-008-0971-1
34. [34]
  X.M. Xie, N.H. Chen, B.H. Guo, S. Li, Polym. Int. 49(2000) 1677-1683. doi: 10.1002/(ISSN)1097-0126
35. [35]
  Y. Li, X.M. Xie, B.H. Guo, Polymer 42(2001) 3419-3425. doi: 10.1016/S0032-3861(00)00767-9
36. [36]
  X.M. Xie, Y. Li, J.C. Zhang, X. Yang, Acta Polym. Sin. 33(2002) 7-12.
37. [37]
  D. Wang, X.M. Xie, Polymer 47(2006) 7859-7863. doi: 10.1016/j.polymer.2006.09.026
38. [38]
  Y. Li, D. Wang, J.M. Zhang, X.M. Xie, J. Appl. Polym. Sci. 119(2011) 1652-1658. doi: 10.1002/app.v119:3
39. [39]
  Y. Li, D. Wang, J.M. Zhang, X.M. Xie, Polym. Bull. 66(2011) 841-852. doi: 10.1007/s00289-010-0380-0
40. [40]
  D. Wang, Y. Li, X.M. Xie, B.H. Guo, Polymer 52(2011) 191-200. doi: 10.1016/j.polymer.2010.11.019
41. [41]
  H. Li, X. Sui, X.M. Xie, Polymer 123(2017) 240-246. doi: 10.1016/j.polymer.2017.07.024
42. [42]
  H. Li, X.M. Xie, Polymer 108(2017) 1-10. doi: 10.1016/j.polymer.2016.11.044
43. [43]
  H. Li, X. Sui, X.M. Xie, Chin. J. Polym Sci. 36(2018) 848-858. doi: 10.1007/s10118-018-2102-2
44. [44]
  C. Li, Y. Zhang, Y. Zhang, Polym. Test. 22(2003) 191-195. doi: 10.1016/S0142-9418(02)00079-X
45. [45]
  W.C. Shi, G.H. Fredrickson, E.J. Kramer, et al., ACS Nano 10(2016) 2054-2062. doi: 10.1021/acsnano.5b06215
46. [46]
  C.B. Bucknall, D.R. Paul, Polymer 50(2009) 5539-5548. doi: 10.1016/j.polymer.2009.09.059
47. [47]
  C.B. Bucknall, D.R. Paul, Polymer 54(2013) 320-329. doi: 10.1016/j.polymer.2012.11.019
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