Citation: Yu Huanan, Xia Huicong, Zhang Jianan, He Jing, Guo Shiyu, Xu Qun. Fabrication of Fe-doped Co-MOF with mesoporous structure for the optimization of supercapacitor performances[J]. Chinese Chemical Letters, ;2018, 29(6): 834-836. doi: 10.1016/j.cclet.2018.04.008 shu

Fabrication of Fe-doped Co-MOF with mesoporous structure for the optimization of supercapacitor performances

Yu Huanan ^a,1 ,
Xia Huicong ^a,1 ,
Zhang Jianan ^a,b,, ,
He Jing ^a ,
Guo Shiyu ^a ,
Xu Qun ^a,,

a.
College of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
b.
Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), Nankai University, Tianjin 300071, China

Corresponding author: Zhang Jianan, Xu Qun, zjn@zzu.edu.cn; qunxu@zzu.edu.cn

Received Date: 13 December 2017
Revised Date: 29 March 2018
Accepted Date: 30 March 2018
Available Online: 7 June 2018
Fund Project: College of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China

Figures(4)

The synergy effect between different components has attracted widespread attentions because of improved activity, selectivity and stability than single component. In this paper, we fabricated mesoporous hybrid dual-metal Co and Fe containing metallic organic framework (Co/Fe-MOF), Fe-MOF, and Co-MOF in the ionic liquid (IL)/supercritical CO₂ (SC)/surfactant emulsion system, and then studied the electrochemical properties of the three MOFs systematically. Experiment results indicate that, by taking advantages of coexistence of double metal, hybrid bi-metal Co/Fe-MOF exhibits the highest specific capacitance and the best cycling stability, with specific capacitance to 319.5 F/g at 1 A/g, 1.4 and 4 times for single Co-MOF and Fe-MOF, respectively.
- Metallic organic framework,
- Mesoporous structure,
- Synergistic effect,
- Hybrid dual-metal,
- Supercapacitor
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