Citation: Yang Qi, Wang Bin, Chen Ya, Xie Yabo, Li Jianrong. An anionic In(III)-based metal-organic framework with Lewis basic sites for the selective adsorption and separation of organic cationic dyes[J]. Chinese Chemical Letters, ;2019, 30(1): 234-238. doi: 10.1016/j.cclet.2018.03.023 shu

An anionic In(III)-based metal-organic framework with Lewis basic sites for the selective adsorption and separation of organic cationic dyes

Beijing Key Laboratory for Green Catalysis and Separation and Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China

Corresponding author: Xie Yabo, xieyabo@bjut.edu.cn
Received Date: 25 December 2017
Revised Date: 10 February 2018
Accepted Date: 19 March 2018
Available Online: 26 January 2018

Figures(4)

In this paper, a new anionic metal-organic framework, [In(PBPTTBA)] [(CH₃)₂NH₂] (BUT-29) has been synthesized through the reaction of tetratopic acid ligand with double Lewis pyridine sites, 4,4',4",4'"-(4,4'-(1,4-phenylene)bis(pyridine-6,4,2-triyl)) tetrabenzoic acid (H₄PBPTTBA) and In(NO₃)₂·5H₂O and fully characterized by single-crystal X-ray diffraction (SXRD), powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), infrared spectroscopy (IR), and elemental analysis (EA). BUT-29 can be used as an efficient adsorbent for the selective removal of organic cationic dyes in N, N'-dimethylformamide (DMF) solution. The adsorption capacities of BUT-29 toward methylene blue and crystal violet at 298 K can reach 1119 mg/g and 832 mg/g, respectively. Moreover, the adsorbed dyes can be released in the DMF solution of LiNO₃ gradually.
- Anionic metal-organic framework,
- Lewis basic sites,
- Selective adsorption,
- Separation,
- Organic dye
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