Citation: He Denghong, Wu Xiaolin, Liu Wei, Lei Chaojun, Yu Chunlin, Zheng Guokui, Pan Junjie, Lei Lecheng, Zhang Xingwang. Co_1-xS embedded in porous carbon derived from metal organic framework as a highly efficient electrocatalyst for oxygen evolution reaction[J]. Chinese Chemical Letters, ;2019, 30(1): 229-233. doi: 10.1016/j.cclet.2018.03.020 shu

Co_1-xS embedded in porous carbon derived from metal organic framework as a highly efficient electrocatalyst for oxygen evolution reaction

Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Zhang Xingwang, xwzhang@zju.edu.cn
Received Date: 6 February 2018
Revised Date: 13 March 2018
Accepted Date: 16 March 2018
Available Online: 17 January 2018

Figures(4)

Developing active, robust, and cost-efficient electrocatalysts is critical for oxygen evolution reaction (OER). Here, a novel composite catalyst of Co_1-xS embedded in porous dodecahedron carbon hybrid was synthesized by a two-step conversion protocol of a cobalt-based metal-organic framework (ZIF-67). The porous dodecahedron Co_1-xS@C composite catalyst was prepared by direct oxidation of ZIF-67 followed by sulfurization reaction. The Co_1-xS@C composite exhibit superior OER performance, including a low overpotential of 260 mV for 10 mA/cm², a small Tafel slope of 85 mV/dec, outstanding stability over 80 h and almost 100% Faradaic efficiency. The various material characterizations indicate that the excellent activity and strong stability of Co_1-xS@C might be attributed to good conductivity of Co_1-xS, mesoporous nanostructure, and synergistic effect of Co_1-xS encapsulated within porous carbon. This work provides a novel strategy for designing and synthesizing advanced composite electrocatalysts.
- Cobalt sulfides,
- Metal organic framework,
- Porous composite catalyst,
- Oxygen evolution reaction,
- Electrochemical water splitting
1. [1]
  Y. Na, B. Hu, Q.L. Yang, et al., Chin. Chem. Lett. 26(2015) 141-144. doi: 10.1016/j.cclet.2014.09.011
2. [2]
  X. Zou, Y. Zhang, Chem. Soc. Rev. 44(2015) 5148-5180. doi: 10.1039/C4CS00448E
3. [3]
  P.E. Dodds, I. Staffell, A.D. Hawkes, et al., Int. J. Hydrogen Energy 40(2015) 2065-2083. doi: 10.1016/j.ijhydene.2014.11.059
4. [4]
  L.A. Stern, L. Feng, F. Song, et al., Energy Environ. Sci. 8(2015) 2347-2351. doi: 10.1039/C5EE01155H
5. [5]
  D.J. Li, U.N. Maiti, J. Lim, et al., Nano Lett. 14(2014) 1228-1233. doi: 10.1021/nl404108a
6. [6]
  C. Tang, H.S. Wang, H.F. Wang, et al., Adv. Mater. 27(2015) 4516-4522. doi: 10.1002/adma.v27.30
7. [7]
  Y. Dou, T. Liao, Z. Ma, et al., Nano Energy 30(2016) 267-275. doi: 10.1016/j.nanoen.2016.10.020
8. [8]
  L. Xu, Q. Jiang, Z. Xiao, et al., Angew. Chem. 128(2016) 5363-5367. doi: 10.1002/ange.201600687
9. [9]
  Z. Xiao, Y. Wang, Y.C. Huang, et al., Energy Environ. Sci. 10(2017) 2563-2569. doi: 10.1039/C7EE01917C
10. [10]
  J. Jiang, A. Zhang, L. Li, L. Ai, J. Power Sources 278(2015) 445-451. doi: 10.1016/j.jpowsour.2014.12.085
11. [11]
  X.Y. Yu, Y. Feng, B. Guan, X.W. Lou, U. Paik, Energy Environ. Sci. 9(2016) 1246-1250. doi: 10.1039/C6EE00100A
12. [12]
  A. Mendoza-Garcia, D. Su, S. Sun, Nanoscale 8(2016) 3244-3247. doi: 10.1039/C5NR08763E
13. [13]
  Y. Liu, C. Xiao, M. Lyu, et al., Angew. Chem. 127(2015) 11383-11387. doi: 10.1002/ange.201505320
14. [14]
  J.S. Chen, J. Ren, M. Shalom, T. Fellinger, M. Antonietti, ACS Appl. Mater. Interfaces 8(2016) 5509-5516. doi: 10.1021/acsami.5b10099
15. [15]
  T.Y. Ma, J.L. Cao, M. Jaroniec, S.Z. Qiao, Angew. Chem. Int. Ed. 55(2016) 1138-1142. doi: 10.1002/anie.201509758
16. [16]
  P. Chen, K. Xu, Z. Fang, et al., Angew. Chem. 127(2015) 14923-14927. doi: 10.1002/ange.201506480
17. [17]
  Y. Liu, H. Cheng, M. Lyu, et al., J. Am. Chem. Soc. 136(2014) 15670-15675. doi: 10.1021/ja5085157
18. [18]
  A.T. Swesi, J. Masud, M. Nath, Energy Environ. Sci. 9(2016) 1771-1782. doi: 10.1039/C5EE02463C
19. [19]
  A. Grimaud, K.J. May, C.E. Carlton, et al., Nat. Commun. 4(2013) 2439. doi: 10.1038/ncomms3439
20. [20]
  S. Chen, J. Duan, M. Jaroniec, S. Z. Qiao, Adv. Mater. 26(2014) 2925-2930. doi: 10.1002/adma.v26.18
21. [21]
  J. Zhang, Z. Zhao, Z. Xia, L. Dai, Nat. Nanotechnol. 10(2015) 444. doi: 10.1038/nnano.2015.48
22. [22]
  J. Yang, G. Zhu, Y. Liu, et al., Adv. Funct. Mater. 26(2016) 4712-4721. doi: 10.1002/adfm.v26.26
23. [23]
  J. Jiang, C. Yan, X. Zhao, et al., Green Chem. 19(2017) 3023-3031. doi: 10.1039/C7GC01012E
24. [24]
  P. Cai, J. Huang, J. Chen, Z. Wen, Angew. Chem. Int. Ed. 56(2017) 4858-4861. doi: 10.1002/anie.201701280
25. [25]
  B. Dong, X. Zhao, G.Q. Han, et al., J. Mater. Chem. A 4(2016) 13499-13508. doi: 10.1039/C6TA03177C
26. [26]
  S. Dou, L. Tao, J. Huo, S. Wang, L. Dai, Energy Environ. Sci. 9(2016) 1320-1326. doi: 10.1039/C6EE00054A
27. [27]
  P. Ganesan, M. Prabu, J. Sanetuntikul, S. Shanmugam, ACS Catal. 5(2015) 3625-3637. doi: 10.1021/acscatal.5b00154
28. [28]
  M. Shen, C. Ruan, Y. Chen, et al., ACS Appl. Mater. Inter. 7(2015) 1207-1218. doi: 10.1021/am507033x
29. [29]
  X. Long, J. Li, S. Xiao, et al., Angew. Chem. 126(2014) 7714-7718. doi: 10.1002/ange.201402822
30. [30]
  T. Xia, J. Wang, K. Jiang, et al., Chin. Chem. Lett. 29(2018) 861-864. doi: 10.1016/j.cclet.2017.10.038
31. [31]
  S. Zheng, H. Xue, H. Pang, Coord. Chem. Rev. 373(2018) 2-21. doi: 10.1016/j.ccr.2017.07.002
32. [32]
  S. Zheng, X. Li, B. Yan, et al., Adv. Energy Mater. 7(2017) 1602733. doi: 10.1002/aenm.201602733
33. [33]
  Y. Wang, L. Tao, Z. Xiao, R. Chen, Z. Jiang, S. Wang, Adv. Funct. Mater. 28(2018) 1705356. doi: 10.1002/adfm.v28.11
34. [34]
  H. Liang, L. Li, F. Meng, L. Dang, J. Zhuo, Chem. Mater. 27(2015) 5702-5711. doi: 10.1021/acs.chemmater.5b02177
35. [35]
  B. Chen, R. Li, G. Ma, et al., Nanoscale 7(2015) 20674-20684. doi: 10.1039/C5NR07429K
36. [36]
  A. Aijaz, J. Masa, C. Rösler, et al., Angew. Chem. Int. Ed. 55(2016) 4087-4091. doi: 10.1002/anie.201509382
37. [37]
  C. Sun, Q. Dong, J. Yang, et al., Nano Res. 9(2016) 2234-2243. doi: 10.1007/s12274-016-1110-1
38. [38]
  Z. Zhang, J. Hao, W. Yang, J. Tang, ChemCatChem 7(2015) 1920-1925. doi: 10.1002/cctc.v7.13
39. [39]
  J. Shao, Z. Wan, H. Liu, et al., J. Mater. Chem. A 2(2014) 12194-12200. doi: 10.1039/C4TA01966K
40. [40]
  W. Zeng, G. Zhang, X. Wu, et al., J. Mater. Chem. A 3(2015) 24033-24040. doi: 10.1039/C5TA05934H
41. [41]
  Y. Hou, J. Li, Z. Wen, et al., Nano Energy 12(2015) 1-8. doi: 10.1016/j.nanoen.2014.11.043
42. [42]
  S. Liu, J. Wang, J. Wang, et al., CrystEngComm 16(2014) 814-819. doi: 10.1039/C3CE41915K
43. [43]
  J. Zhu, Z. Ren, S. Du, et al., Nano Res. 10(2017) 1819-1831. doi: 10.1007/s12274-017-1511-9
44. [44]
  C. Wu, Y. Zhang, D. Dong, H. Xie, J. Li, Nanoscale 9(2017) 12432-12440. doi: 10.1039/C7NR03950F
45. [45]
  M. Chauhan, K.P. Reddy, C.S. Gopinath, S. Deka, ACS Catal. 7(2017) 5871-5879. doi: 10.1021/acscatal.7b01831
46. [46]
  Y. Kim, J.B. Goodenough, J. Phys. Chem. C 112(2008) 15060-15064. doi: 10.1021/jp8038847
47. [47]
  N. Jiang, L. Bogoev, M. Popova, et al., J. Mater. Chem. A 2(2014) 19407-19414. doi: 10.1039/C4TA04339A
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Co1-xS embedded in porous carbon derived from metal organic framework as a highly efficient electrocatalyst for oxygen evolution reaction

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通讯作者: 陈斌, bchen63@163.com

Co_1-xS embedded in porous carbon derived from metal organic framework as a highly efficient electrocatalyst for oxygen evolution reaction