Citation: Zhao Zhenshuai, Ye Yihua, Zhu Weihua, Xiao Liang, Deng Bohua, Liu Jinping. Bismuth oxide nanoflake@carbon film: A free-standing battery-type electrode for aqueous sodium ion hybrid supercapacitors[J]. Chinese Chemical Letters, ;2018, 29(4): 629-632. doi: 10.1016/j.cclet.2018.01.011 shu

Bismuth oxide nanoflake@carbon film: A free-standing battery-type electrode for aqueous sodium ion hybrid supercapacitors

Zhao Zhenshuai ^a ,
Ye Yihua ^a ,
Zhu Weihua ^a ,
Xiao Liang ^a ,
Deng Bohua ^a,, ,
Liu Jinping ^a,b,,

a.
School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, Wuhan 430070, China
b.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

Corresponding author: Deng Bohua, dengbh@qq.com Liu Jinping, liujp@whut.edu.cn
Received Date: 9 November 2017
Revised Date: 4 January 2018
Accepted Date: 5 January 2018
Available Online: 6 April 2018

Figures(5)

Aqueous hybrid supercapacitors are promising due to their low cost and high safety. Herein, a freestanding battery-type electrode of Bi₂O₃ nanoflake@C on carbon cloth is designed for aqueous sodium ion hybrid supercapacitors. Due to the integration of nanoarray architecture and the conductive carbon, the Bi₂O₃@C electrode exhibits a high specific capacity of 207 mAh/g at 2 A/g (6C), good rate capability and cycling stability (133 mAh/g after 1000 cycles). With the activated carbon as the capacitive electrode and neutral sodium salts as the electrolyte, a 1.9 V hybrid supercapacitor is assembled, delivering a high energy density of 18.94 Wh/kg. The device can still maintain 72.3% of initial capacity after 650 cycles. The present work holds great promise for developing next-generation hybrid supercapacitors.
- Bi₂O₃ film,
- Free-standing,
- Carbon hybridization,
- Hybrid supercapacitors
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