Citation: Yao Lanqian, Cheng Tao, Shen Xiaoqin, Zhang Yizhou, Lai Wenyong, Huang Wei. Paper-based all-solid-state flexible asymmetric micro-supercapacitors fabricated by a simple pencil drawing methodology[J]. Chinese Chemical Letters, ;2018, 29(4): 587-591. doi: 10.1016/j.cclet.2018.01.007 shu

Paper-based all-solid-state flexible asymmetric micro-supercapacitors fabricated by a simple pencil drawing methodology

Yao Lanqian ^a,1 ,
Cheng Tao ^a,1 ,
Shen Xiaoqin ^a ,
Zhang Yizhou ^a ,
Lai Wenyong ^a,, ,
Huang Wei ^a,b

a.
Key Laboratory for Organic Electronics and Information Displays(KLOEID), Institute of Advanced Materials(IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China
b.
Shaanxi Institute of Flexible Electronics(SIFE), Northwestern Polytechnical University(NPU), Xi'an 710072, China

Corresponding author: Lai Wenyong, iamwylai@njupt.edu.cn

Received Date: 29 October 2017
Revised Date: 3 January 2018
Accepted Date: 4 January 2018
Available Online: 5 April 2018

Figures(5)

Flexible micro-scale energy storage devices as the key component to power the flexible miniaturized electronic devices are attracting extensive attention. In this study, interdigitated asymmetric all-solidstate flexible micro-supercapacitors (MSCs) were fabricated by a simple pencil drawing process followed by electrodepositing MnO₂ on one of the as-drawn graphite electrode as anode and the other as cathode. The as-prepared electrodes showed high areal specific capacitance of 220 μF/cm² at 2.5 μA/cm². The energy density and the corresponding power density of the resultant asymmetrical flexible MSCs were up to 110 μWh/cm² and 1.2 μW/cm², respectively. Furthermore, excellent cycling performance (91% retention of capacity after 1000 cycles) was achieved. The resultant devices also exhibited good electrochemical stability under bending conditions, demonstrating superior flexibility. This study provides a simple yet efficient methodology for designing and fabricating flexible supercapacitors applicable for portable and wearable electronics.
- Flexible electronics,
- Flexible supercapacitors,
- Micro-supercapacitors,
- Paper-based electronics,
- Pencil drawing
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