Citation: Ge Yanqin, Diao Pinhui, Xu Chen, Zhang Nannan, Guo Cheng. Visible light induced cross-coupling synthesis of asymmetrical heterobiaryls using Pd/CeO₂ nanocomposite photocatalyst[J]. Chinese Chemical Letters, ;2018, 29(6): 903-906. doi: 10.1016/j.cclet.2018.01.002 shu

Visible light induced cross-coupling synthesis of asymmetrical heterobiaryls using Pd/CeO₂ nanocomposite photocatalyst

College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China

Corresponding author: Guo Cheng, guocheng@njtech.edu.cn

Received Date: 13 November 2017
Revised Date: 8 December 2017
Accepted Date: 2 January 2018
Available Online: 3 June 2018

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A simple, mild and green approach has been developed for the synthesis of asymmetrical heterobiaryls under the irradiation of visible light without any oxidants and promoting reagents through using Pd/CeO₂ nanocomposite photocatalyst. This method can tolerate considerable functional groups such as electrondonating groups and electron-withdrawing groups through C—C cross-coupling. Moreover, we obtain the products with moderate yields in an efficient way. Finally, a plausible mechanism is proposed.
- Visible light,
- Nanocomposite photocatalyst,
- Pd/CeO₂,
- C—C cross-coupling,
- Mild condition
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沈阳化工大学材料科学与工程学院沈阳 110142

Visible light induced cross-coupling synthesis of asymmetrical heterobiaryls using Pd/CeO2 nanocomposite photocatalyst

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通讯作者: 陈斌, bchen63@163.com

Visible light induced cross-coupling synthesis of asymmetrical heterobiaryls using Pd/CeO₂ nanocomposite photocatalyst