Citation: Li Jie, Wang Yecheng, Yu Yan, Li Qiaowei. Functionality proportion and corresponding stability study of multivariate metal-organic frameworks[J]. Chinese Chemical Letters, ;2018, 29(6): 837-841. doi: 10.1016/j.cclet.2017.12.026 shu

Functionality proportion and corresponding stability study of multivariate metal-organic frameworks

Li Jie ^a ,
Wang Yecheng ^b ,
Yu Yan ^c ,
Li Qiaowei ^a,,

a.
Department of Chemistry, iChEM(Collaborative Innovation Center of Chemistry for Energy Materials), Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China
b.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
c.
School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China

Corresponding author: Li Qiaowei,
Received Date: 18 October 2017
Revised Date: 21 November 2017
Accepted Date: 28 December 2017
Available Online: 29 June 2017

Figures(5)

Multivariate metal-organic frameworks (MTV-MOFs) with different ratios of terephthalate (BDC) linker and amino-benzenedicarboxylate (BDC-NH₂) linker were synthesized through both direct synthesis from linker mixture and linker exchange of activated single-linker MOFs. Functionality proportion was impacted by the thermodynamics during the one-pot MOF construction, resulting in preference of BDC over BDC-NH₂ in the MTV-MOF, in agreement with the quantum mechanics calculations. The functionality difference also affects the thermodynamics in the linker exchange process, as indicated by the more effective linker exchange in BDC-NH₂-based IRMOF-3 than in BDC-based MOF-5. Furthermore, the thermal decomposition temperatures and chemical integrity upon ambient air exposure of these MOFs with variate functionalities were investigated, and it reveals that higher proportion of BDC in the MTV-MOF crystals contribute to both higher thermal and higher chemical stabilities.
- Multivariate metal-organic frameworks,
- Direct synthesis,
- Linker exchange,
- Functionality proportion
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