Citation: Zhao Fangyuan, Zhao Xin, Peng Bo, Gan Feng, Yao Mengyao, Tan Wenjun, Dong Jie, Zhang Qinghua. Polyimide-derived carbon nanofiber membranes as anodes for high-performance flexible lithium ion batteries[J]. Chinese Chemical Letters, ;2018, 29(11): 1692-1697. doi: 10.1016/j.cclet.2017.12.015 shu

Polyimide-derived carbon nanofiber membranes as anodes for high-performance flexible lithium ion batteries

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China

Corresponding author: Zhao Xin, xzhao@dhu.edu.cn Zhang Qinghua, qhzhang@dhu.edu.cn
Received Date: 6 November 2017
Revised Date: 4 December 2017
Accepted Date: 22 December 2017
Available Online: 26 November 2017

Figures(6)

The strategy of N-doping in carbon materials could provide additional Li-ion storage sites to improve their electrochemical properties. Heteroatom-containing polymers could serve as good precursors to fabricate doped carbons due to the capability to in situ dope heteroatoms into the structures. In this work, electrospun heterocyclic polyimide (PI) nanofiber membranes containing biphenyl and pyrimidine rings were carbonized to fabricate freestanding and flexible heteroatoms-containing carbon membranes. When the polymer membranes were subjected to various calcination temperatures (from 550℃ to 950℃) and durations (0.5-10 h), the structural evolutions strongly affect their electrochemical properties as anodes for lithium ion batteries. It demonstrated that the reversible specific capacity of obtained sample treated at 650℃ for 3 h could achieve 695 mAh/g at 0.1 A/g and retain 245 mAh/g at 1.5 A/g after 300 cycles. Furthermore, the electrospun membrane maintains a good electrochemical performance at bending state as a flexible electrode.
- Heteroatom,
- Nanofiber,
- Polyimide,
- Anode,
- Lithium ion battery
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