Citation: Fan Weidong, Wang Yutong, Xiao Zhenyu, Huang Zhaodi, Dai Fangna, Wang Rongming, Sun Daofeng. Two-dimensional cobalt metal-organic frameworks for efficient C₃H₆/CH₄ and C₃H₈/CH₄ hydrocarbon separation[J]. Chinese Chemical Letters, ;2018, 29(6): 865-868. doi: 10.1016/j.cclet.2017.11.020 shu

Two-dimensional cobalt metal-organic frameworks for efficient C₃H₆/CH₄ and C₃H₈/CH₄ hydrocarbon separation

State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum(East China), Qingdao 266580, China

Corresponding author: Dai Fangna, fndai@upc.edu.cn Sun Daofeng, dfsun@upc.edu.cn
Received Date: 31 August 2017
Revised Date: 12 November 2017
Accepted Date: 14 November 2017
Available Online: 20 June 2017

Figures(4)

A Co-based two-dimensional (2D) microporous metal-organic frameworks, [Co₂(TMTA)(DMF)₂(H₂O)₂] NO₃^- DMF (UPC-32) has been synthesized based on 4, 4', 4"-(2, 4, 6-trimethylbenzene-1, 3, 5-triyl) tribenzoic acid (H₃TMTA). UPC-32 features a 2D microporous framework exhibits high adsorption of H₂ (118.2 cm³/g, 1.05 wt%, at 77 K), and adsorption heat (Q_st) of CO₂ (34-46 kJ/mol). UPC-32 with narrow distance between layers (3.8 Å) exhibits high selectivity of C₃H₆/CH₄ (31.46) and C₃H₈/CH₄ (28.04) at 298 K and 1 bar. It is the first 2D Co-MOF that showed selective separation of C3 hydrocarbon from CH₄.
- Metal-organic frameworks,
- Microporous,
- Two-dimensional,
- Selective separation
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Two-dimensional cobalt metal-organic frameworks for efficient C3H6/CH4 and C3H8/CH4 hydrocarbon separation

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Two-dimensional cobalt metal-organic frameworks for efficient C₃H₆/CH₄ and C₃H₈/CH₄ hydrocarbon separation