Citation: Qi Yan-Jie, Liu Jin-Hua, Zheng Wen-Xu, Li Xin-Xiong, Zheng Shou-Tian. A rare porous zinc phosphonocarboxylate framework with high thermal stability and interesting structural transformation[J]. Chinese Chemical Letters, ;2018, 29(6): 959-962. doi: 10.1016/j.cclet.2017.09.060 shu

A rare porous zinc phosphonocarboxylate framework with high thermal stability and interesting structural transformation

State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350108, China

Corresponding author: Zheng Shou-Tian, stzheng@fzu.edu.cn
Received Date: 13 July 2017
Revised Date: 12 September 2017
Accepted Date: 29 September 2017
Available Online: 28 June 2017

Figures(3)

A rare porous zinc-organic framework with ultrahigh thermal stability over 500℃ was obtained, which exhibits a CaF₂-type topology formed by 8-connected tetranuclear Zn₄ clusters and 4-connected phosphonocarboxylate ligands. Interestingly, the similar reactions to the zinc-organic framework but in the absence of H₂O or by the replacement of Zn²⁺ with Co²⁺ can yield three different 3D cluster-based frameworks but with the same CaF₂-type topology.
- Phosphonocarboxylate ligand,
- Metal-organic framework,
- Stability,
- Structural transformation,
- Gas adsorption
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