Citation: Huang Dandan, Wu Xueqian, Tian Junwu, Wang Xiaokun, Zhou Zhihang, Li Dongsheng. Assembling of a novel 3D Ag(Ⅰ)-MOFs with mixed ligands tactics: Syntheses, crystal structure and catalytic degradation of nitrophenol[J]. Chinese Chemical Letters, ;2018, 29(6): 845-848. doi: 10.1016/j.cclet.2017.09.043 shu

Assembling of a novel 3D Ag(Ⅰ)-MOFs with mixed ligands tactics: Syntheses, crystal structure and catalytic degradation of nitrophenol

a.
College of Materials and Chemical Engineering, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, Hubei Provincial Collaborative Innovation Center for New Energy Microgrid, China Three Gorges University, Yichang 443002, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Li Dongsheng, lidongsheng1@126.com
Received Date: 27 July 2017
Revised Date: 1 September 2017
Accepted Date: 21 September 2017
Available Online: 28 June 2017

Figures(2)

A silver-based metal-organic framework (Ag-MOFs), [Ag₂(H₃ddcba)(dpp)₂] (1) (H₅ddcba=3, 5-(di(2', 5'-dicarboxylphenyl)benozoic acid, dpp=1, 3-di(4-pyridyl)propane), was successfully constructed via hydrothermal assembly of a pentacaboxylate ligand, a N-donor ligand and Ag(Ⅰ) ions, which possesses a pcu topology and exhibits excellent catalytic properties in aqueous solution for the degradation of o-nitrophenol (2-NP), m-nitrophenol (3-NP) and p-nitrophenol (4-NP). Related kinetics of such catalytic reactions, photoluminescent and thermal stability of compound 1 were also investigated.
- Ag(Ⅰ) metal organic framework,
- Mixed ligands tactics,
- Crystal structure,
- Nitrophenol,
- Catalytic properties
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