Citation: Zhang Shan, Wang Xiang, Zhang Hui-Xiu, Zhao Zi-Hui, Wang Xiu-Li. Solvent-tuned polyoxometalate-based supramolecular hybrids constructed from different metal-organic motifs: Various structures and adsorption properties for dyes[J]. Chinese Chemical Letters, ;2018, 29(2): 309-312. doi: 10.1016/j.cclet.2017.08.044 shu

Solvent-tuned polyoxometalate-based supramolecular hybrids constructed from different metal-organic motifs: Various structures and adsorption properties for dyes

Department of Chemistry, Bohai University, Jinzhou 121000, China

Corresponding author: Wang Xiang, xwang@bhu.edu.cn Wang Xiu-Li, wangxiuli@bhu.edu.cn
Received Date: 28 June 2017
Revised Date: 2 August 2017
Accepted Date: 16 August 2017
Available Online: 4 February 2017

Figures(4)

By changing the solvents, three polyoxometalate (POM)-based supramolecular hybrids, [Co₂L₃] [SiW₁₂O₄₀]·17H₂O (1), [Co₂L₂(H₂O)₄] [SiW₁₂O₄₀]·2EtOH·2H₂O (2) and[Co₂L₃] [SiW₁₂O₄₀]·9DMA·6H₂O (3), have been synthesized under hydrothermal or solvothermal conditions. All three hybrids show various supramolecular structures, which contain two kinds of different metal-organic motifs. A kind of metal-organic cationic cage[Co₂L₃]⁴⁺ is formed in the presence of H₂O for 1, DMA/H₂O for 3, and a metalorganic cationic circle[Co₂L₂]⁴⁺ is constructed in the presence of EtOH/H₂O for 2. That is to say, the solvents show a key role in tuning the architectures of metal-organic fragments and the final POM-based supramolecular structures. The adsorption properties of 1-3 for different organic dyes have also been investigated.
- Polyoxometalate,
- Solvent-tuned,
- Bis-imidazolyl-bis-amide ligand,
- Dyes adsorption,
- Supramolecular hybrids
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