Citation: Qin Jieqiong, Wu Zhong-Shuai, Zhou Feng, Dong Yanfeng, Xiao Han, Zheng Shuanghao, Wang Sen, Shi Xiaoyu, Huang Haibo, Sun Chenglin, Bao Xinhe. Simplified fabrication of high areal capacitance all-solid-state micro-supercapacitors based on graphene and MnO₂ nanosheets[J]. Chinese Chemical Letters, ;2018, 29(4): 582-586. doi: 10.1016/j.cclet.2017.08.007 shu

Simplified fabrication of high areal capacitance all-solid-state micro-supercapacitors based on graphene and MnO₂ nanosheets

Qin Jieqiong ^a,c ,
Wu Zhong-Shuai ^a,, ,
Zhou Feng ^a ,
Dong Yanfeng ^a ,
Xiao Han ^a ,
Zheng Shuanghao ^a,b,c ,
Wang Sen ^a,c ,
Shi Xiaoyu ^a,b,d ,
Huang Haibo ^a ,
Sun Chenglin ^a ,
Bao Xinhe ^a,b

a.
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
b.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China
d.
Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China

Corresponding author: Wu Zhong-Shuai, wuzs@dicp.ac.cn
Received Date: 18 May 2017
Revised Date: 2 August 2017
Accepted Date: 4 August 2017
Available Online: 12 April 2017

Figures(4)

All-solid-state micro-supercapacitors are acknowledged as a very promising class of microscale energy storage devices for directly integrating portable and wearable electronics. However, the improvement of electrochemical performance from materials to devices still remains tremendous challenges. Here, we demonstrate a novel and universal mask-assisted filtration technology for the simplified fabrication of all-solid-state planar micro-supercapacitors (MSCs) based on interdigital patterns of 2D pseudocapacitive MnO₂ nanosheets and electrochemically exfoliated graphene film as both electrode and current collector, and polyvinyl alcohol/LiCl gel as electrolyte. Remarkably, the resulting MSCs exhibit outstanding areal capacitance of ~355 mF/cm², which is among the highest values reported in the state-of-the-art MSCs. Meanwhile, MSCs possess exceptionally mechanical flexibility as high as 92% of initial capacitance even at a highly bending angle of 180, excellent cyclability with a capacitance retention of 95% after 3000 cycles, and impressive serial or parallel integration for modulating the voltage or capacitance. Therefore, our proposed strategy of simplified construction of MSCs will pave the ways for utilizing graphene and analogous pseudocapactive nanosheets in high-performance MSCs.
- MnO₂ nanosheets,
- Graphene,
- All-solid-state,
- Planar,
- Micro-supercapacitors,
- Energy storage
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沈阳化工大学材料科学与工程学院沈阳 110142

Simplified fabrication of high areal capacitance all-solid-state micro-supercapacitors based on graphene and MnO2 nanosheets

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通讯作者: 陈斌, bchen63@163.com

Simplified fabrication of high areal capacitance all-solid-state micro-supercapacitors based on graphene and MnO₂ nanosheets