Citation: Wang Jilei, Li Shang, Liang Ruiqi, Wu Bing, He Yaning. Synthesis and characterization of water-soluble PEGylated lignin-based polymers by macromolecular azo coupling reaction[J]. Chinese Chemical Letters, ;2018, 29(1): 143-146. doi: 10.1016/j.cclet.2017.07.008 shu

Synthesis and characterization of water-soluble PEGylated lignin-based polymers by macromolecular azo coupling reaction

Department of Chemical Engineering, Key Laboratory of Advanced Materials(MOE), Tsinghua University, Beijing 100084, China

Corresponding author: He Yaning, heyaning@mail.tsinghua.edu.cn
Received Date: 24 April 2017
Revised Date: 15 May 2017
Accepted Date: 5 July 2017
Available Online: 11 January 2017

Figures(4)

Water-soluble PEG grafted lignin-based polymers (AL-azo-PEG) were efficiently synthesized by macromolecular azo coupling reaction between alkali lignin and PEG based macromolecular diazonium salts in alkaline water. This one-step PEGylation method showed many advantages such as high efficiency, controllable grafting radio, extremely mild conditions and without organic solvents. The prepared AL-azo-PEG polymers were well characterized by using various spectroscopic methods including UV-vis, FTIR and ¹H NMR spectra. Experimental results showed that the synthesized polymers had good solubility both in water over a wide pH range (pH 2-12) and in the majority of organic solvents, which helped to easily fabricate self-assembly colloidal particles and nanofibers by vapor diffusion method and electrospinning method, respectively. The azobenzene linkages generated by the macromolecular azo coupling reaction also brought photo-responsive properties to the prepared polymers.
- Lignin-based polymers,
- Water-soluble,
- Macromolecular azo coupling reaction,
- Colloid particles,
- Nanofibers
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