Citation: Yang Yifan, Zheng Qing, Yan Yuanyuan, Liu Yao, Shao Huibo. The enhanced electronic communication in ferrocenemethanol molecular cluster based on intermolecular hydrogen-bonding[J]. Chinese Chemical Letters, ;2018, 29(1): 179-182. doi: 10.1016/j.cclet.2017.06.011 shu

The enhanced electronic communication in ferrocenemethanol molecular cluster based on intermolecular hydrogen-bonding

Key Laboratory of Cluster Science(Ministry of Education) and Beijing Key Laboratory of Photoelectronic and Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China

Corresponding author: Shao Huibo, hbs@bit.edu.cn
Received Date: 25 March 2017
Revised Date: 1 May 2017
Accepted Date: 7 June 2017
Available Online: 9 January 2017

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This work presents an electrochemical study of enhanced electronic communication based on intermolecular hydrogen-bonding in ferrocenemethanol (described as FcCH₂OH) molecular clusters. The enhanced electronic communication in FcCH₂OH clusters is confirmed and further investigated by differential-pulse voltammetry and cyclic voltammetry. A key finding is that this enhanced electronic communication increases the standard rate constant of the electron transfer process. These results will provide us with a further understanding of the electronic communication within the ferrocenyl derivatives which is based on the intermolecular hydrogen-bonding.
- Enhanced electronic communication,
- Intermolecular hydrogen-bonding,
- Molecular clusters,
- Electron transfer,
- Cyclic voltammetry
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