Citation: Yin Zhi-Jian, Wu Zong-Quan, Lin Feng, Qi Qiao-Yan, Xu Xiao-Na, Zhao Xin. A supramolecular bottlebrush polymer assembled on the basis of cucurbit[8]uril-encapsulation-enhanced donor-acceptor interaction[J]. Chinese Chemical Letters, ;2017, 28(6): 1167-1171. doi: 10.1016/j.cclet.2017.03.029 shu

A supramolecular bottlebrush polymer assembled on the basis of cucurbit[8]uril-encapsulation-enhanced donor-acceptor interaction

Yin Zhi-Jian ^a,b ,
Wu Zong-Quan ^a ,
Lin Feng ^b ,
Qi Qiao-Yan ^b ,
Xu Xiao-Na ^b,, ,
Zhao Xin ^b,,

a.
Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, China
b.
Key Laboratory of Synthetic and Self-assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Corresponding author: Xu Xiao-Na, xuxiaona@sioc.ac.cn Zhao Xin, xzhao@sioc.ac.cn; xinzhao72@yahoo.com
Received Date: 6 February 2017
Revised Date: 1 March 2017
Accepted Date: 17 March 2017
Available Online: 22 June 2017

Figures(6)

A supramolecular bottlebrush polymer has been constructed in water through the self-assembly of a rigid electron-deficient building block and an electron-rich monomer which bears two tetraethylene glycol chains, driven by CB[8]-encapsulation-enhanced donor-acceptor interaction. The as-formed supramolecular bottlebrush polymer has been characterized by ¹H NMR titration experiment, UV-vis spectroscopy, DLS and 2D ¹H NMR DOSY.
- Self-assembly,
- Supramolecular polymer,
- Cucurbit[8]uril,
- Donor-acceptor interaction,
- Bottlebrush polymer
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