Citation: Gao Yu-Ning, Shi Min. Phosphine-mediated enantioselective synthesis of carbocycles and heterocycles[J]. Chinese Chemical Letters, ;2017, 28(3): 493-502. doi: 10.1016/j.cclet.2016.12.001 shu

Phosphine-mediated enantioselective synthesis of carbocycles and heterocycles

Gao Yu-Ning ,
Shi Min ^,

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Corresponding author: Shi Min, mshi@sioc.ac.cn
Received Date: 24 October 2016
Revised Date: 15 November 2016
Accepted Date: 28 November 2016
Available Online: 9 March 2016

Figures(21)

Nucleophilic chiral phosphine catalysis has been prosperous in asymmetric synthesis over the past two decades. Various tunable chiral phosphines display excellent activity and selectivity in asymmetric transformations including acycloaddition reactions and cycloaddition reactions. Enantiomerically enriched cyclic compounds are ubiquitous in natural products and drug molecules. These phosphinecatalyzed reactions provide effective and extensive strategies for the synthesis of a series of complex cyclic compounds as well as the synthesis of chiral compounds which could be easily transformed to carbocycles and heterocycles. This minireview summarizes recent developments in this area and highlights meaningful breakthroughs.
- Bifunctional phosphines,
- Asymmetric catalysis,
- Carbocycles,
- Heterocycles,
- Cycloaddition reactions
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沈阳化工大学材料科学与工程学院沈阳 110142